Onkarabile G. Pooe, Saheed E. Elugoke, Gloria E. Uwaya, Omolola E. Fayemi
{"title":"多壁碳纳米管/CuO纳米复合修饰铂电极上辣椒素的电化学测定","authors":"Onkarabile G. Pooe, Saheed E. Elugoke, Gloria E. Uwaya, Omolola E. Fayemi","doi":"10.1007/s10876-025-02767-5","DOIUrl":null,"url":null,"abstract":"<div><p>Herein, electrochemical detection of capsaicin (CAP) in sauce and rub samples at a Pt electrode modified with copper oxide nanoparticles (CuO NPs) incorporated with functionalized multi-walled carbon nanotubes (fMWCNTs) was reported. The spectroscopic and microscopic characterization of CuO NPs, fMWCNTs and CuO/fMWCNTs nanocomposite with scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) spectroscopy and Fourier-transform infrared spectroscopy (FT-IR) spectroscopy confirmed that CuO/fMWCNTs was prepared from the nanomaterials. Electrochemical characterization of the bare Pt, the fMWCNTs-modified Pt, the CuO NP-modified Pt (Pt-CuO) and the CuO/fMWCNTs composite modified Pt (Pt-CuO/fMWCNTs) electrodes revealed that the Pt-CuO/fMWCNTs exhibited the best electron transfer capabilities. The limit of detection (LOD) and the linear range of CAP at Pt-CuO/fMWCNTs were 0.0881 and 0.357–2.73 µM, respectively. The proposed sensor offered outstanding percentage recovery of 106 and 102% when applied to the electroanalysis of CAP in spiked sauce and rub samples, respectively. Pt-CuO/fMWCNTs also retained about 88% of its initial current response when subjected to 25 cyclic voltammetry (CV) scans in the presence of CAP.</p></div>","PeriodicalId":618,"journal":{"name":"Journal of Cluster Science","volume":"36 2","pages":""},"PeriodicalIF":3.6000,"publicationDate":"2025-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10876-025-02767-5.pdf","citationCount":"0","resultStr":"{\"title\":\"Electrochemical Determination of Capsaicin at A Multiwalled Carbon Nanotubes/CuO Nanocomposite Modified Platinum Electrode\",\"authors\":\"Onkarabile G. Pooe, Saheed E. Elugoke, Gloria E. Uwaya, Omolola E. Fayemi\",\"doi\":\"10.1007/s10876-025-02767-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Herein, electrochemical detection of capsaicin (CAP) in sauce and rub samples at a Pt electrode modified with copper oxide nanoparticles (CuO NPs) incorporated with functionalized multi-walled carbon nanotubes (fMWCNTs) was reported. The spectroscopic and microscopic characterization of CuO NPs, fMWCNTs and CuO/fMWCNTs nanocomposite with scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) spectroscopy and Fourier-transform infrared spectroscopy (FT-IR) spectroscopy confirmed that CuO/fMWCNTs was prepared from the nanomaterials. Electrochemical characterization of the bare Pt, the fMWCNTs-modified Pt, the CuO NP-modified Pt (Pt-CuO) and the CuO/fMWCNTs composite modified Pt (Pt-CuO/fMWCNTs) electrodes revealed that the Pt-CuO/fMWCNTs exhibited the best electron transfer capabilities. The limit of detection (LOD) and the linear range of CAP at Pt-CuO/fMWCNTs were 0.0881 and 0.357–2.73 µM, respectively. The proposed sensor offered outstanding percentage recovery of 106 and 102% when applied to the electroanalysis of CAP in spiked sauce and rub samples, respectively. Pt-CuO/fMWCNTs also retained about 88% of its initial current response when subjected to 25 cyclic voltammetry (CV) scans in the presence of CAP.</p></div>\",\"PeriodicalId\":618,\"journal\":{\"name\":\"Journal of Cluster Science\",\"volume\":\"36 2\",\"pages\":\"\"},\"PeriodicalIF\":3.6000,\"publicationDate\":\"2025-02-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://link.springer.com/content/pdf/10.1007/s10876-025-02767-5.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Cluster Science\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10876-025-02767-5\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Cluster Science","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10876-025-02767-5","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Electrochemical Determination of Capsaicin at A Multiwalled Carbon Nanotubes/CuO Nanocomposite Modified Platinum Electrode
Herein, electrochemical detection of capsaicin (CAP) in sauce and rub samples at a Pt electrode modified with copper oxide nanoparticles (CuO NPs) incorporated with functionalized multi-walled carbon nanotubes (fMWCNTs) was reported. The spectroscopic and microscopic characterization of CuO NPs, fMWCNTs and CuO/fMWCNTs nanocomposite with scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) spectroscopy and Fourier-transform infrared spectroscopy (FT-IR) spectroscopy confirmed that CuO/fMWCNTs was prepared from the nanomaterials. Electrochemical characterization of the bare Pt, the fMWCNTs-modified Pt, the CuO NP-modified Pt (Pt-CuO) and the CuO/fMWCNTs composite modified Pt (Pt-CuO/fMWCNTs) electrodes revealed that the Pt-CuO/fMWCNTs exhibited the best electron transfer capabilities. The limit of detection (LOD) and the linear range of CAP at Pt-CuO/fMWCNTs were 0.0881 and 0.357–2.73 µM, respectively. The proposed sensor offered outstanding percentage recovery of 106 and 102% when applied to the electroanalysis of CAP in spiked sauce and rub samples, respectively. Pt-CuO/fMWCNTs also retained about 88% of its initial current response when subjected to 25 cyclic voltammetry (CV) scans in the presence of CAP.
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