Mengyin Liao, Chao Wang, Xuanhua Zhang, Chao Luan, Wenyuan Xu and ZhongYi He
{"title":"Pt/Co(OH) 2-NiO /C催化剂的制备及其对甲醇的电催化氧化","authors":"Mengyin Liao, Chao Wang, Xuanhua Zhang, Chao Luan, Wenyuan Xu and ZhongYi He","doi":"10.1039/D4NJ04094E","DOIUrl":null,"url":null,"abstract":"<p >Novel Pt/Co(OH)<small><sub>2</sub></small>–NiO/C catalysts based on carbon black were successfully synthesized using the hydrazine hydrate reduction method and galvanic replacement strategies. They were subsequently tested for their activity in the electrocatalytic oxidation of methanol. It was observed that the peak current density of Pt/Co(OH)<small><sub>2</sub></small>–NiO/C (8.29 A mg<small><sub>Pt</sub></small><small><sup>−1</sup></small>) was 22.4 times higher than that of commercial Pt/C-JM (0.37 A mg<small><sub>Pt</sub></small><small><sup>−1</sup></small>). The electrocatalytic activities and durabilities of the synchronously synthesized Pt/Co(OH)<small><sub>2</sub></small>–NiO/C catalysts were significantly better than those of PtCo/C, PtNi/C, and PtCoNi/C-<em>X</em> (<em>X</em> = 200, 400, 600) catalysts synthesized by calcination in Ar at different temperatures. The reason is that the highly dispersed Pt helps to expose more active sites on the catalyst surface, and the addition of Co(OH)<small><sub>2</sub></small> and NiO alters the electron density of Pt, which reduces the adsorption of intermediate CO, attenuates the toxic effect, and enables more efficient oxidation of methanol.</p>","PeriodicalId":95,"journal":{"name":"New Journal of Chemistry","volume":" 6","pages":" 2224-2230"},"PeriodicalIF":2.5000,"publicationDate":"2025-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation of Pt/Co(OH)2–NiO/C catalysts and their electrocatalytic oxidation of methanol\",\"authors\":\"Mengyin Liao, Chao Wang, Xuanhua Zhang, Chao Luan, Wenyuan Xu and ZhongYi He\",\"doi\":\"10.1039/D4NJ04094E\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Novel Pt/Co(OH)<small><sub>2</sub></small>–NiO/C catalysts based on carbon black were successfully synthesized using the hydrazine hydrate reduction method and galvanic replacement strategies. They were subsequently tested for their activity in the electrocatalytic oxidation of methanol. It was observed that the peak current density of Pt/Co(OH)<small><sub>2</sub></small>–NiO/C (8.29 A mg<small><sub>Pt</sub></small><small><sup>−1</sup></small>) was 22.4 times higher than that of commercial Pt/C-JM (0.37 A mg<small><sub>Pt</sub></small><small><sup>−1</sup></small>). The electrocatalytic activities and durabilities of the synchronously synthesized Pt/Co(OH)<small><sub>2</sub></small>–NiO/C catalysts were significantly better than those of PtCo/C, PtNi/C, and PtCoNi/C-<em>X</em> (<em>X</em> = 200, 400, 600) catalysts synthesized by calcination in Ar at different temperatures. The reason is that the highly dispersed Pt helps to expose more active sites on the catalyst surface, and the addition of Co(OH)<small><sub>2</sub></small> and NiO alters the electron density of Pt, which reduces the adsorption of intermediate CO, attenuates the toxic effect, and enables more efficient oxidation of methanol.</p>\",\"PeriodicalId\":95,\"journal\":{\"name\":\"New Journal of Chemistry\",\"volume\":\" 6\",\"pages\":\" 2224-2230\"},\"PeriodicalIF\":2.5000,\"publicationDate\":\"2025-01-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"New Journal of Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/nj/d4nj04094e\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"New Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/nj/d4nj04094e","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
采用水合肼还原法制备了新型Pt/Co(OH) 2-NiO /C催化剂。随后测试了它们在甲醇电催化氧化中的活性。结果表明,Pt/Co(OH) 2-NiO /C的峰值电流密度(8.29 A mgPt−1)比商用Pt/C- jm的峰值电流密度(0.37 A mgPt−1)高22.4倍。同步合成的Pt/Co(OH) 2-NiO /C催化剂的电催化活性和耐用性均显著优于不同温度下在Ar中煅烧合成的PtCo/C、PtNi/C和PtCoNi/C-X (X = 200、400、600)催化剂。这是因为高度分散的Pt有助于在催化剂表面暴露更多的活性位点,而Co(OH)2和NiO的加入改变了Pt的电子密度,从而减少了中间Co的吸附,减弱了毒性作用,使甲醇的氧化效率更高。
Preparation of Pt/Co(OH)2–NiO/C catalysts and their electrocatalytic oxidation of methanol
Novel Pt/Co(OH)2–NiO/C catalysts based on carbon black were successfully synthesized using the hydrazine hydrate reduction method and galvanic replacement strategies. They were subsequently tested for their activity in the electrocatalytic oxidation of methanol. It was observed that the peak current density of Pt/Co(OH)2–NiO/C (8.29 A mgPt−1) was 22.4 times higher than that of commercial Pt/C-JM (0.37 A mgPt−1). The electrocatalytic activities and durabilities of the synchronously synthesized Pt/Co(OH)2–NiO/C catalysts were significantly better than those of PtCo/C, PtNi/C, and PtCoNi/C-X (X = 200, 400, 600) catalysts synthesized by calcination in Ar at different temperatures. The reason is that the highly dispersed Pt helps to expose more active sites on the catalyst surface, and the addition of Co(OH)2 and NiO alters the electron density of Pt, which reduces the adsorption of intermediate CO, attenuates the toxic effect, and enables more efficient oxidation of methanol.