钍的地球化学性质与矿化

Jie Li , Tianhui Bai , Wenxuan Hu , Meiyun Wang , Lei Liao , Zhifeng Xun , Zexin Wang , Hao Song
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摘要

钍是一种天然存在的放射性元素,广泛分布在不同的地质环境中。钍是一种典型的亲石元素,对氧具有很强的亲和力,容易与硅酸盐熔体结合,主要集中在岩石圈中。在岩浆阶段,钍的地球化学行为与U、Ce、Zr相似,是一种不相容元素,存在于岩浆演化后期的残余熔体中。钍在酸性、伟晶岩和碱性岩石中富集,从而形成含钍的磷矿物,如独居石。碱性碳酸岩流体富集稀土元素和钍,将钍矿床与火成岩碳酸岩紧密联系在一起。在地表过程中,钍的地球化学性质相对惰性,使其能够保存在含钍矿物的稳定晶格中并形成砂矿。在全球范围内,钍资源主要存在于碳酸盐岩、砂矿和脉状矿床中,其中独居石是主要来源之一。根据国际原子能机构和核能机构联合发布的一份报告,目前全球钍资源超过630万吨,主要分布在印度、巴西、澳大利亚和美国等国家。钍的成矿期主要集中在前寒武纪和中生代,其次是古生代和新生代。在中国,钍资源相对丰富,多与稀土元素矿床有关,但受分选技术等因素的影响,利用率较低。钍是空间技术工业的重要原料,也是未来重要的核燃料;因此,应加强钍资源的合理开发和战略保护,并建立适当的战略储备。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Geochemical properties and mineralization of thorium
Thorium, a naturally occurring radioactive element, is widely distributed across diverse geological environments. As a typical lithophilic element, thorium exhibits strong affinity towards oxygen, readily integrating into silicate melts, primarily concentrating in the lithosphere. During the magmatic phase, thorium's geochemical behavior is akin to that of U, Ce, and Zr, and as an incompatible element, it remains in the residual melts of the latter stages of magmatic evolution. Thorium is enriched in acidic, pegmatitic, and alkaline rocks, leading to the formation of thorium-bearing phosphate minerals such as monazite. Alkaline carbonatitic fluids are capable of enriching rare earth elements and thorium, closely associating thorium deposits with igneous carbonatites. In surface processes, thorium's geochemical properties are relatively inert, allowing it to be preserved within the stable lattice of thorium-bearing minerals and form placer deposits. Globally, thorium resources are primarily found in carbonatite rocks, placer, and vein deposits, with monazite being one of the main sources. According to a report jointly published by the International Atomic Energy Agency and the Nuclear Energy Agency, the global thorium resources currently exceed 6.3 million tons, predominantly distributed in countries like India, Brazil, Australia, and the United States. The mineralization period of thorium is mainly concentrated in the Precambrian and Mesozoic, followed by the Paleozoic and Cenozoic. In China, thorium resources are relatively abundant, mostly associated with rare earth element deposits, yet their utilization rate remains low due to factors such as sorting technology. Thorium is a vital raw material in the space technology industry and a significant future nuclear fuel; thus, rational development and strategic protection of thorium resources should be strengthened, along with appropriate strategic reserves.
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