Baoyang Dai, Shanshan Yan, Zhimi Chen, Tucai Zheng, Jie Qin, Junhua Zhao, Wanting Jin, Chunhui Zhou, Li Wan, Xing Su and Chuanhua Gao*,
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Synthesis of Symmetrical Silane Containing P═O Bonds and Their Passivation of Perovskites
Perovskite quantum dots (QDs) exhibit unique advantages, including a wide color gamut, narrow full width at half-maximum, cost-effectiveness, and high-efficiency luminescence, positioning them as a significant focus in contemporary optoelectronic research. Nevertheless, the synthesis of QDs often introduces crystal defects, while conventional in situ ligands can detrimentally affect the optoelectronic properties of perovskites. To overcome these challenges, we synthesized a symmetrical silane-based passivating agent containing phosphorus–oxygen double bonds. This agent enabled the in situ passivation of perovskites, significantly improving their optical performance and stability. Results showed that postpassivation QDs demonstrated bright green photoluminescence (PL) at 525 nm, with a 28% enhancement in PL intensity, a 16% increase in photoluminescence quantum yield, and an average lifetime (τave) extended by 191.2 ns. Furthermore, the thermal stability at 80 °C improved by 3.75-fold, and the stability under 84% relative humidity conditions increased by 21%. 1,3-bis(3-diethoxyphosphorylpropyl)-1,1,3,3-tetramethyldisiloxane (SPE)-passivated perovskites are viable for practical applications.
ACS OmegaChemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍:
ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.