金属配体双功能铱催化剂催化常压下2,5-呋喃二乙醛还原胺化制N,N ' -二取代2,5-双(氨基甲基)呋喃

IF 7.3 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Heng You, Beixuan Dong, Jinci Liang, Liangshun Guo, Qixun Shi and Feng Li*, 
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引用次数: 0

摘要

以[Cp*Ir(2,2 ' -bpyO)(H2O)]为催化剂,在常压氢气条件下完成了2,5-呋喃二醛还原胺化制N,N'-二取代2,5-二(氨基甲基)呋喃的反应。配体中的官能团是催化剂活性的关键因素。此外,还对该体系进行了机理研究、实际应用以及其它生物基糠醛的还原胺化反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Reductive Amination of 2,5-Furandicarbaldehyde to N,N’-Disubstituted 2,5-Bis(aminomethyl)furan under Atmospheric Pressure of Hydrogen Gas Catalyzed by a Metal–Ligand Bifunctional Iridium Catalyst

Reductive Amination of 2,5-Furandicarbaldehyde to N,N’-Disubstituted 2,5-Bis(aminomethyl)furan under Atmospheric Pressure of Hydrogen Gas Catalyzed by a Metal–Ligand Bifunctional Iridium Catalyst

The reductive amination of 2,5-furandicarbaldehyde to N,N'-disubstituted 2,5-bis(aminomethyl)furan under atmospheric pressure of hydrogen gas has been accomplished using [Cp*Ir(2,2′-bpyO)(H2O)] as a catalyst. Functional groups in the ligand are a critical factor for the activity of the catalyst. Furthermore, the mechanistic investigation, the practical application of this system, and the reductive amination of other biobased furfuryl aldehydes were also undertaken.

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来源期刊
ACS Sustainable Chemistry & Engineering
ACS Sustainable Chemistry & Engineering CHEMISTRY, MULTIDISCIPLINARY-ENGINEERING, CHEMICAL
CiteScore
13.80
自引率
4.80%
发文量
1470
审稿时长
1.7 months
期刊介绍: ACS Sustainable Chemistry & Engineering is a prestigious weekly peer-reviewed scientific journal published by the American Chemical Society. Dedicated to advancing the principles of green chemistry and green engineering, it covers a wide array of research topics including green chemistry, green engineering, biomass, alternative energy, and life cycle assessment. The journal welcomes submissions in various formats, including Letters, Articles, Features, and Perspectives (Reviews), that address the challenges of sustainability in the chemical enterprise and contribute to the advancement of sustainable practices. Join us in shaping the future of sustainable chemistry and engineering.
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