中-4,5-环氧环己烯的区域发散不对称反应

IF 3.6 2区化学 Q1 CHEMISTRY, ORGANIC

Journal of Organic Chemistry Pub Date : 2024-12-26 DOI:10.1021/acs.joc.4c0221410.1021/acs.joc.4c02214

Yiwei Wang, Miho Wakiya, Ryosuke Matsubara and Masahiko Hayashi*,

引用次数: 0

摘要

在此，我们报道了中-4,5-环氧环己烯的区域分散脱对称，这导致一个化合物在单一手性催化剂下形成两个对映体富集的高对映选择性结构异构体。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Regiodivergent Desymmetrization of meso-4,5-Epoxycyclohex-1-ene

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Regiodivergent Desymmetrization of meso-4,5-Epoxycyclohex-1-ene

Herein, we report a regiodivergent desymmetrization of meso-4,5-epoxycyclohex-1-ene, which results in the formation of two enantioenriched structural isomers with high enantioselectivity from a single compound using a single chiral catalyst.

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来源期刊

Journal of Organic Chemistry 化学-有机化学

CiteScore

6.20

自引率

11.10%

发文量

1467

审稿时长

2 months

期刊介绍： Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.