外加磁场下随机各向异性驱动的一阶磁跃迁巨磁熵变化

IF 6.3 2区 材料科学 Q2 CHEMISTRY, PHYSICAL
Phong H. Nguyen , Niem T. Nguyen , Huy D. Nguyen , Hoai T.L. Nguyen , Cong T. Bach , Giang H. Bach
{"title":"外加磁场下随机各向异性驱动的一阶磁跃迁巨磁熵变化","authors":"Phong H. Nguyen ,&nbsp;Niem T. Nguyen ,&nbsp;Huy D. Nguyen ,&nbsp;Hoai T.L. Nguyen ,&nbsp;Cong T. Bach ,&nbsp;Giang H. Bach","doi":"10.1016/j.jallcom.2025.179001","DOIUrl":null,"url":null,"abstract":"<div><div>First-order magnetic transition (FOMT) and isothermal first-order magnetization process (FOMP) were investigated for a two-dimensional (2D) spin system using the Monte Carlo simulation for the spin <em>S</em> = 1 Blume-Capel model with random anisotropy in an external magnetic field. Within this framework, giant changes in isothermal magnetic entropy occur near the FOMT critical temperature <span><math><msubsup><mrow><mi>T</mi></mrow><mrow><mi>C</mi></mrow><mrow><mrow><mo>(</mo><mrow><mn>1</mn></mrow><mo>)</mo></mrow></mrow></msubsup></math></span> when the magnitude of the random anisotropy <em>D</em> and its probability <em>p</em> is sufficiently large. The behavior of the FOMT is observed not only by a sudden drop of magnetic moment at a critical temperature <span><math><msubsup><mrow><mi>T</mi></mrow><mrow><mi>C</mi></mrow><mrow><mrow><mo>(</mo><mrow><mn>1</mn></mrow><mo>)</mo></mrow></mrow></msubsup></math></span> but also by redistributing energy and magnetic moment histograms. From that, we successfully produce a phase diagram illustrating a random-anisotropy-driven second-order magnetic transition (SOMT) to FOMT in comparison with Ref. <span><span>[1]</span></span>. Magnetic entropy change (∣Δ<em>S</em><sub><em>M</em></sub>∣) calculations indicate that a giant magnetocaloric effect at a low magnetic field occurs very close to <span><math><msubsup><mrow><mi>T</mi></mrow><mrow><mi>C</mi></mrow><mrow><mrow><mo>(</mo><mrow><mn>1</mn></mrow><mo>)</mo></mrow></mrow></msubsup></math></span> when its strength approaches the critical field <em>h</em><sub><em>cr</em></sub> of the FOMP. Besides, the ∣Δ<em>S</em><sub><em>M</em></sub>∣ in the FOMT is much larger than in the second-order magnetic transition at the same low field. We also conduct calculation comparisons about the temperature dependence of magnetic behavior near the FOMT with experimental observations for Cr<sub>11</sub>Ge<sub>19</sub> samples.</div></div>","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"1017 ","pages":"Article 179001"},"PeriodicalIF":6.3000,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Random-anisotropy driven giant magnetic entropy change in first-order magnetic transition under external fields\",\"authors\":\"Phong H. Nguyen ,&nbsp;Niem T. Nguyen ,&nbsp;Huy D. Nguyen ,&nbsp;Hoai T.L. Nguyen ,&nbsp;Cong T. Bach ,&nbsp;Giang H. Bach\",\"doi\":\"10.1016/j.jallcom.2025.179001\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>First-order magnetic transition (FOMT) and isothermal first-order magnetization process (FOMP) were investigated for a two-dimensional (2D) spin system using the Monte Carlo simulation for the spin <em>S</em> = 1 Blume-Capel model with random anisotropy in an external magnetic field. Within this framework, giant changes in isothermal magnetic entropy occur near the FOMT critical temperature <span><math><msubsup><mrow><mi>T</mi></mrow><mrow><mi>C</mi></mrow><mrow><mrow><mo>(</mo><mrow><mn>1</mn></mrow><mo>)</mo></mrow></mrow></msubsup></math></span> when the magnitude of the random anisotropy <em>D</em> and its probability <em>p</em> is sufficiently large. The behavior of the FOMT is observed not only by a sudden drop of magnetic moment at a critical temperature <span><math><msubsup><mrow><mi>T</mi></mrow><mrow><mi>C</mi></mrow><mrow><mrow><mo>(</mo><mrow><mn>1</mn></mrow><mo>)</mo></mrow></mrow></msubsup></math></span> but also by redistributing energy and magnetic moment histograms. From that, we successfully produce a phase diagram illustrating a random-anisotropy-driven second-order magnetic transition (SOMT) to FOMT in comparison with Ref. <span><span>[1]</span></span>. Magnetic entropy change (∣Δ<em>S</em><sub><em>M</em></sub>∣) calculations indicate that a giant magnetocaloric effect at a low magnetic field occurs very close to <span><math><msubsup><mrow><mi>T</mi></mrow><mrow><mi>C</mi></mrow><mrow><mrow><mo>(</mo><mrow><mn>1</mn></mrow><mo>)</mo></mrow></mrow></msubsup></math></span> when its strength approaches the critical field <em>h</em><sub><em>cr</em></sub> of the FOMP. Besides, the ∣Δ<em>S</em><sub><em>M</em></sub>∣ in the FOMT is much larger than in the second-order magnetic transition at the same low field. We also conduct calculation comparisons about the temperature dependence of magnetic behavior near the FOMT with experimental observations for Cr<sub>11</sub>Ge<sub>19</sub> samples.</div></div>\",\"PeriodicalId\":344,\"journal\":{\"name\":\"Journal of Alloys and Compounds\",\"volume\":\"1017 \",\"pages\":\"Article 179001\"},\"PeriodicalIF\":6.3000,\"publicationDate\":\"2025-02-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Alloys and Compounds\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0925838825005596\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Alloys and Compounds","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0925838825005596","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

摘要

采用蒙特卡罗模拟方法研究了具有随机各向异性的自旋S = 1 Blume-Capel模型在外加磁场作用下的一阶磁跃迁(FOMT)和等温一阶磁化过程(FOMP)。在此框架下,当随机各向异性D的幅度及其概率p足够大时,在fmt临界温度TC(1)附近,等温磁熵发生巨大变化。fft的行为不仅可以通过临界温度TC(1)下磁矩的突然下降来观察,还可以通过能量和磁矩直方图的重新分布来观察。由此,我们成功地制作了一个相位图,说明了与Ref.[1]相比,随机各向异性驱动的二阶磁跃迁(SOMT)到fmt。磁熵变化(∣ΔSM∣)计算表明,当低磁场强度接近FOMP的临界场hcr时,在TC(1)附近会发生巨大的磁热效应。此外,在相同的低场下,fft中的∣ΔSM∣比二阶磁跃迁中的大得多。我们还对Cr11Ge19样品在fmt附近的磁性行为的温度依赖性与实验观测进行了计算比较。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Random-anisotropy driven giant magnetic entropy change in first-order magnetic transition under external fields
First-order magnetic transition (FOMT) and isothermal first-order magnetization process (FOMP) were investigated for a two-dimensional (2D) spin system using the Monte Carlo simulation for the spin S = 1 Blume-Capel model with random anisotropy in an external magnetic field. Within this framework, giant changes in isothermal magnetic entropy occur near the FOMT critical temperature TC(1) when the magnitude of the random anisotropy D and its probability p is sufficiently large. The behavior of the FOMT is observed not only by a sudden drop of magnetic moment at a critical temperature TC(1) but also by redistributing energy and magnetic moment histograms. From that, we successfully produce a phase diagram illustrating a random-anisotropy-driven second-order magnetic transition (SOMT) to FOMT in comparison with Ref. [1]. Magnetic entropy change (∣ΔSM∣) calculations indicate that a giant magnetocaloric effect at a low magnetic field occurs very close to TC(1) when its strength approaches the critical field hcr of the FOMP. Besides, the ∣ΔSM∣ in the FOMT is much larger than in the second-order magnetic transition at the same low field. We also conduct calculation comparisons about the temperature dependence of magnetic behavior near the FOMT with experimental observations for Cr11Ge19 samples.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Journal of Alloys and Compounds
Journal of Alloys and Compounds 工程技术-材料科学:综合
CiteScore
11.10
自引率
14.50%
发文量
5146
审稿时长
67 days
期刊介绍: The Journal of Alloys and Compounds is intended to serve as an international medium for the publication of work on solid materials comprising compounds as well as alloys. Its great strength lies in the diversity of discipline which it encompasses, drawing together results from materials science, solid-state chemistry and physics.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信