由天然化合物构成的无卤化物深共晶溶剂，用于将二氧化碳转化为环状碳酸盐

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-01-29 DOI:10.1039/D4CC06282E

Wen-Wang Yu, Xiang-Guang Meng, Wen Li, Jie Zhou, Xian-Jian Ma and Dan-Dan Chu

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引用次数: 0

摘要

采用源自天然生物化合物的无卤化物深度共晶溶剂（DESs）温和催化CO2与环氧化物的环加成反应，TOF为645 h−1。DFT计算结果与实验结果吻合较好，表明环闭合过程是速率决定步骤。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Halide-free deep eutectic solvents constructed from natural compounds for converting carbon dioxide to cyclic carbonate†

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Halide-free deep eutectic solvents constructed from natural compounds for converting carbon dioxide to cyclic carbonate†

Halide-free deep eutectic solvents (DESs) derived from natural biological compounds were used to gently catalyze the cycloaddition reaction between CO₂ and epoxides, with a TOF of 645 h⁻¹. The DFT calculation result was in good agreement with the experiment result, indicating that the ring closure process was the rate-determining step.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.