砷形态分析技术。

IF 1.8 4区 化学 Q3 CHEMISTRY, ANALYTICAL
Yu-ki Tanaka, Kemmu Matsuhashi, Yasumitsu Ogra
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引用次数: 0

摘要

砷是一类致癌物,由于其毒性,砷污染是一个重大的环境和公共卫生问题。砷的毒性因其化学形态而异。例如,亚砷酸盐(AsO33-)和砷酸盐(AsO43-)等无机物质通常比有机砷化合物毒性更大。然而,一些有机砷种类表现出比无机种类更高的毒性。因此,砷的精确定量和形态是必要的。色谱技术,特别是液相色谱-电感耦合等离子体质谱(LC-ICP-MS),由于其高灵敏度和准确性,被广泛用于砷的形态分析。气相色谱-质谱法(GC-MS)是衍生化后检测砷种类的另一种有效技术。除了色谱法,更直接和成本效益的技术可用于无机砷形态。这些方法包括吸附技术、比色法(如钼蓝法)、氢化物生成反应和伏安法。新兴技术,如微流体和电化学装置,实现了快速和便携式分析,促进了环境样品中亚砷酸盐和砷酸盐的原位检测。虽然LC-ICP-MS仍然是全面砷形态分析的金标准,但其他先进技术提供了一种实用、快速和经济有效的方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Analytical techniques for arsenic speciation

Due to its toxicity, contamination with arsenic, a Group 1 carcinogen, is a significant environmental and public health issue. The toxicity of arsenic varies with its chemical form. For example, inorganic species like arsenite (AsO33−) and arsenate (AsO43−) are generally more toxic than organoarsenic compounds. However, some organoarsenic species exhibit higher toxicity than inorganic species. Therefore, the precise quantification and speciation of arsenic is necessary. Chromatographic techniques, particularly liquid chromatography coupled with inductively coupled plasma mass spectrometry (LC-ICP-MS), are widely used for arsenic speciation owing to their high sensitivity and accuracy. Gas chromatography-mass spectrometry (GC-MS) is another effective technique for detecting arsenic species after derivatization. In addition to chromatographic methods, more straightforward and cost-effective techniques are available for inorganic arsenic speciation. These include adsorption techniques, colorimetric assays such as the molybdenum blue method, hydride generation reactions, and voltammetry. Emerging technologies, such as microfluidic and electrochemical devices, enable rapid and portable analysis, facilitating in situ detection of arsenite and arsenate in environmental samples. While LC-ICP-MS remains the gold standard for comprehensive arsenic speciation, other advanced technologies provide a practical, rapid, and cost-effective approach.

Graphical Abstract

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来源期刊
Analytical Sciences
Analytical Sciences 化学-分析化学
CiteScore
2.90
自引率
18.80%
发文量
232
审稿时长
1 months
期刊介绍: Analytical Sciences is an international journal published monthly by The Japan Society for Analytical Chemistry. The journal publishes papers on all aspects of the theory and practice of analytical sciences, including fundamental and applied, inorganic and organic, wet chemical and instrumental methods. This publication is supported in part by the Grant-in-Aid for Publication of Scientific Research Result of the Japanese Ministry of Education, Culture, Sports, Science and Technology.
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