评估用于越野和建筑应用的低氮氧化物氢发动机。

IF 4.3 3区 环境科学与生态学 Q1 CHEMISTRY, ANALYTICAL
Lucy J. Webster, Ryan Ballard, Tom Beamish, Tim Burnhope, Jack Humbert, Alastair C. Lewis, Jakub Piaszyk and Sarah J. Moller
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引用次数: 0

摘要

氢内燃机为非道路移动机械(NRMM)等难以电气化的行业提供了短期脱碳途径。然而,很少有氢专用发动机能够实现最大限度地提高低碳能源效率和提供空气质量的双重目标。我们分析了一款适用于NRMM行业各种用途的~ 55 kW四缸喷油火花点火式氢内燃机(H2ICE)的四种型号的测功仪衍生的氮氧化物(NOx)尾气排放。据报道,其中一种H2ICE型号的发动机输出(预处理后)排放也有所增加。研究人员将非道路瞬态循环(NRTC)下的排放与符合当代第五阶段排放标准的55 kW柴油发动机进行了比较。与柴油发动机相比,所有四种H2ICE型号都被配置为在稀薄燃烧条件下运行,通过NRTC产生的NOx废气排放量大大降低。经过选择性催化还原和微粒过滤器(SCRF)后处理的火花点火H2ICE的NOx排放量最低。在全NRTC配置下,该配置的尾气NOx排放量为1.90 mg kWh-1,与柴油(3340 mg kWh-1)相比减少了99%以上,在所有功率、扭矩和速度设置下,H2ICEs的平均NOx排放量都更低。还比较了柴油和H2ICE的瞬态频率和强度。使用氢滑动催化剂的H2ICE,在没有SCRF后处理的情况下,尾气排放的氮氧化物(NOx)也明显低于柴油当量(63.7 mg kWh-1),比NRTC提高了50倍以上。这就产生了一个系统层面的两难问题:使用SCRF实现的额外的少量氮氧化物绝对减少是否会产生净收益,从而超过SCR和排气液制造、分配以及可能从排气中产生的少量氨泄漏所带来的更广泛的财务和环境成本。无论后处理系统如何,与改用其他低碳替代品(如生物柴油或加氢处理植物油)相比,在NRMM中采用低NOx排放的H2ICE,特别是建筑设备,似乎能在短期内为城市提供更大的空气质量效益。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Evaluating low NOx hydrogen engines designed for off-road and construction applications†

Evaluating low NOx hydrogen engines designed for off-road and construction applications†

Hydrogen internal combustion engines offer a near-term decarbonisation pathway for hard to electrify sectors such as non-road mobile machinery (NRMM). However, few hydrogen-specific engines have ever been developed with the twin-goals of maximising low carbon energy efficiency and delivering air quality co-benefits. We present analyses of dynamometer-derived nitrogen oxides (NOx) tailpipe emissions from four variants of a ∼55 kW four-cylinder port fuelled injection spark ignition hydrogen internal combustion engine (H2ICE) suitable for a range of uses within the NRMM industry. Engine out (pre-aftertreatment) emissions are also reported for one of the H2ICE variants. The emissions were compared over the Non-Road Transient Cycle (NRTC) with an equivalent contemporary Stage V emissions compliant 55 kW diesel engine. All four H2ICE variants were configured to operate under lean burn conditions generating substantially lower NOx exhaust emissions over the NRTC when compared to the diesel engine. Lowest NOx emissions were observed for a spark ignition H2ICE with selective catalytic reduction and particulate filter (SCRF) aftertreatment. Tailpipe NOx emissions over the full NRTC for this configuration were 1.90 mg kWh−1, a greater than 99% reduction compared to diesel (3340 mg kWh−1) with lower average NOx emissions observed for the H2ICEs over all power, torque, and speed settings. The frequency and magnitude of transient (<20 ms) increases in NOx were also compared between diesel and H2ICE. A H2ICE using a hydrogen slip catalyst, but without SCRF aftertreatment, also emitted significantly lower tailpipe NOx than the diesel equivalent (63.7 mg kWh−1), a factor of greater than 50 times improvement over the NRTC. This creates a systems level dilemma: whether the additional small absolute reductions in NOx achieved using SCRF would have a net benefit that outweighed the broader financial and environmental costs of the SCR and exhaust fluid manufacture, distribution and possible small in-service ammonia slip from exhaust. Irrespective of aftertreatment system, the adoption of low NOx emitting H2ICE in NRMM, and particularly construction equipment, would appear to offer much greater near-term air quality benefits for cities when compared to switching to other low carbon alternatives such as biodiesel or hydrotreated vegetable oil.

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来源期刊
Environmental Science: Processes & Impacts
Environmental Science: Processes & Impacts CHEMISTRY, ANALYTICAL-ENVIRONMENTAL SCIENCES
CiteScore
9.50
自引率
3.60%
发文量
202
审稿时长
1 months
期刊介绍: Environmental Science: Processes & Impacts publishes high quality papers in all areas of the environmental chemical sciences, including chemistry of the air, water, soil and sediment. We welcome studies on the environmental fate and effects of anthropogenic and naturally occurring contaminants, both chemical and microbiological, as well as related natural element cycling processes.
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