利用甘氨酸和棕榈基磺酸甲酯(MES)环保型抑制剂改善石蜡沉淀抑制效果。

IF 2.6 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES
PLoS ONE Pub Date : 2025-01-28 eCollection Date: 2025-01-01 DOI:10.1371/journal.pone.0313394
Nazliah Binti Surpina, Mysara Eissa Mohyaldinn, Abdullah Abduljabbar, Mohammed Abdalla Ayoub
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引用次数: 0

摘要

位于寒冷环境和深海的油田,在原油长距离运输过程中,经常面临管道石蜡堆积的挑战。已经采用了各种策略来解决这个问题,其中化学方法是最有效和最经济的。然而,传统的化学抑制剂由于其高毒性和低生物降解性而存在问题,导致操作成本增加和环境问题。本研究的重点是利用三种不同浓度的甘氨酸和棕榈基磺酸甲酯(MES)开发一种环保型石蜡抑制剂体系。对都朗油田的原油样品进行了实验。实验测量包括蜡的外观温度(WAT),倾点温度(PPT),以及在没有和存在所提出的抑制剂的情况下的流变学测试。结果表明,甘氨酸和MES均能有效降低WAT、粘度和屈服点。其中,10%甘氨酸是最佳抑制剂,WAT降低23.3%。然而,MES(1%, 5%和10%)显示出更大的总体有效性,平均WAT降低13.76%,而甘氨酸为10.85%。MES在降低粘度和屈服应力方面也表现出较好的性能。虽然PPT结果不显著,但MES被推荐作为流动改善剂而不是降凝剂。这些新配方的化学抑制剂的成功开发有望成为一种环境可持续、经济高效的方法,在减少石蜡沉淀的同时,最大限度地提高成熟油田的石油产量。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Improving paraffin precipitate inhibition using glycine and Palm-based Methyl Ester Sulfonate (MES) eco-friendly inhibitors.

Oil fields located in cold environments and deep-sea locations often face challenges with paraffin wax buildup in pipelines during long-distance crude oil transportation. Various strategies have been employed to address this issue, with chemical methods being the most effective and economical. However, traditional chemical inhibitors present problems due to their high toxicity and low biodegradability, leading to increased operational costs and environmental concerns. This study focuses on developing an eco-friendly paraffin inhibitor system using three different concentrations of Glycine and Palm-based Methyl Ester Sulfonate (MES). Experiments were conducted on crude oil samples from the Dulang Oilfield. The experimental measurements include wax appearance temperature (WAT), pour point temperature (PPT), and rheological tests in the absence and presence of the proposed inhibitors. The results revealed that both Glycine and MES can effectively reduce WAT, viscosity, and yield point. Specifically, 10% Glycine was the best inhibitor, reducing WAT by 23.3%. However, MES (1%, 5%, and 10%) demonstrated greater overall effectiveness, with an average WAT reduction of 13.76% compared to Glycine's 10.85%. MES also shows a better performance in reducing viscosity and yield stress. While PPT results were insignificant, MES is recommended as a flow improver rather than a pour point depressant. The successful development of these newly formulated chemical inhibitors promises an environmentally sustainable and economically efficient approach to maximizing oil production from mature fields while mitigating paraffin precipitation.

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来源期刊
PLoS ONE
PLoS ONE 生物-生物学
CiteScore
6.20
自引率
5.40%
发文量
14242
审稿时长
3.7 months
期刊介绍: PLOS ONE is an international, peer-reviewed, open-access, online publication. PLOS ONE welcomes reports on primary research from any scientific discipline. It provides: * Open-access—freely accessible online, authors retain copyright * Fast publication times * Peer review by expert, practicing researchers * Post-publication tools to indicate quality and impact * Community-based dialogue on articles * Worldwide media coverage
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