{"title":"Eu3+/Y3+掺杂对SrTiO3钙钛矿荧光粉结构和光学性能的影响及多功能应用","authors":"Satyam Upadhyay , Arpita Dwivedi , Prateek Kumar Yadav , Monika Srivastava , Amit Srivastava , Chandan Upadhyay , S.K. Srivastava","doi":"10.1016/j.jallcom.2025.178866","DOIUrl":null,"url":null,"abstract":"<div><div>A latent fingerprint (LFP) examination is essential for identifying fingerprints at crime sites, and personal data for legal operations requires economical, eco-friendly, and sensitive new materials. Here, a new composition of intense red-emitting Eu<sup>3+</sup> and Y<sup>3+</sup> co-doped SrTiO<sub>3</sub> perovskites nanophosphor synthesized using a modified sol-gel-assisted combustion technique has been reported. To explore the structural and optical features of the nanophosphors the samples are characterized by various techniques. The powder XRD pattern reveals that the approximate crystallite size is 30 nm, which is consistent with TEM. It is found that with the mid- and near-ultraviolet light excitation, Eu<sup>3+</sup> and Y<sup>3+</sup> co-doped SrTiO<sub>3</sub> nanophosphor displays a strong red emission at 618 nm for optimal concentrations (3 mol% Eu). The CIE (0.656, 0.344), color purity 95 %, CRI 98 %, and CCT values 2435 K, which is less than 5000 K reveals that the Eu<sup>3+</sup> and Y<sup>3+</sup> co-doped SrTiO<sub>3</sub> phosphor was highly useful for the fabrication of warm LED and display device applications. Further, the optimized phosphor was tested (under UV light of 254 nm) for the visualization of LFP and security ink on various material surfaces. The results demonstrated that it provides an effective method for visualizing ridge patterns, offering a promising approach for applications in these areas. Based on the findings, Eu<sup>3+</sup> and Y<sup>3+</sup> co-doped SrTiO<sub>3</sub> show potential for various optoelectronic applications, including WLEDs, LFP detection, security inks, and LEDs.</div></div>","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"1016 ","pages":"Article 178866"},"PeriodicalIF":6.3000,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Impact of Eu3 +/Y3+ doping on the structural and optical properties of SrTiO3 perovskite phosphor and multi-functional applications\",\"authors\":\"Satyam Upadhyay , Arpita Dwivedi , Prateek Kumar Yadav , Monika Srivastava , Amit Srivastava , Chandan Upadhyay , S.K. Srivastava\",\"doi\":\"10.1016/j.jallcom.2025.178866\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A latent fingerprint (LFP) examination is essential for identifying fingerprints at crime sites, and personal data for legal operations requires economical, eco-friendly, and sensitive new materials. Here, a new composition of intense red-emitting Eu<sup>3+</sup> and Y<sup>3+</sup> co-doped SrTiO<sub>3</sub> perovskites nanophosphor synthesized using a modified sol-gel-assisted combustion technique has been reported. To explore the structural and optical features of the nanophosphors the samples are characterized by various techniques. The powder XRD pattern reveals that the approximate crystallite size is 30 nm, which is consistent with TEM. It is found that with the mid- and near-ultraviolet light excitation, Eu<sup>3+</sup> and Y<sup>3+</sup> co-doped SrTiO<sub>3</sub> nanophosphor displays a strong red emission at 618 nm for optimal concentrations (3 mol% Eu). The CIE (0.656, 0.344), color purity 95 %, CRI 98 %, and CCT values 2435 K, which is less than 5000 K reveals that the Eu<sup>3+</sup> and Y<sup>3+</sup> co-doped SrTiO<sub>3</sub> phosphor was highly useful for the fabrication of warm LED and display device applications. Further, the optimized phosphor was tested (under UV light of 254 nm) for the visualization of LFP and security ink on various material surfaces. The results demonstrated that it provides an effective method for visualizing ridge patterns, offering a promising approach for applications in these areas. Based on the findings, Eu<sup>3+</sup> and Y<sup>3+</sup> co-doped SrTiO<sub>3</sub> show potential for various optoelectronic applications, including WLEDs, LFP detection, security inks, and LEDs.</div></div>\",\"PeriodicalId\":344,\"journal\":{\"name\":\"Journal of Alloys and Compounds\",\"volume\":\"1016 \",\"pages\":\"Article 178866\"},\"PeriodicalIF\":6.3000,\"publicationDate\":\"2025-01-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Alloys and Compounds\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0925838825004244\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Alloys and Compounds","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0925838825004244","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Impact of Eu3 +/Y3+ doping on the structural and optical properties of SrTiO3 perovskite phosphor and multi-functional applications
A latent fingerprint (LFP) examination is essential for identifying fingerprints at crime sites, and personal data for legal operations requires economical, eco-friendly, and sensitive new materials. Here, a new composition of intense red-emitting Eu3+ and Y3+ co-doped SrTiO3 perovskites nanophosphor synthesized using a modified sol-gel-assisted combustion technique has been reported. To explore the structural and optical features of the nanophosphors the samples are characterized by various techniques. The powder XRD pattern reveals that the approximate crystallite size is 30 nm, which is consistent with TEM. It is found that with the mid- and near-ultraviolet light excitation, Eu3+ and Y3+ co-doped SrTiO3 nanophosphor displays a strong red emission at 618 nm for optimal concentrations (3 mol% Eu). The CIE (0.656, 0.344), color purity 95 %, CRI 98 %, and CCT values 2435 K, which is less than 5000 K reveals that the Eu3+ and Y3+ co-doped SrTiO3 phosphor was highly useful for the fabrication of warm LED and display device applications. Further, the optimized phosphor was tested (under UV light of 254 nm) for the visualization of LFP and security ink on various material surfaces. The results demonstrated that it provides an effective method for visualizing ridge patterns, offering a promising approach for applications in these areas. Based on the findings, Eu3+ and Y3+ co-doped SrTiO3 show potential for various optoelectronic applications, including WLEDs, LFP detection, security inks, and LEDs.
期刊介绍:
The Journal of Alloys and Compounds is intended to serve as an international medium for the publication of work on solid materials comprising compounds as well as alloys. Its great strength lies in the diversity of discipline which it encompasses, drawing together results from materials science, solid-state chemistry and physics.