Eu3+/Y3+掺杂对SrTiO3钙钛矿荧光粉结构和光学性能的影响及多功能应用

IF 6.3 2区 材料科学 Q2 CHEMISTRY, PHYSICAL
Satyam Upadhyay , Arpita Dwivedi , Prateek Kumar Yadav , Monika Srivastava , Amit Srivastava , Chandan Upadhyay , S.K. Srivastava
{"title":"Eu3+/Y3+掺杂对SrTiO3钙钛矿荧光粉结构和光学性能的影响及多功能应用","authors":"Satyam Upadhyay ,&nbsp;Arpita Dwivedi ,&nbsp;Prateek Kumar Yadav ,&nbsp;Monika Srivastava ,&nbsp;Amit Srivastava ,&nbsp;Chandan Upadhyay ,&nbsp;S.K. Srivastava","doi":"10.1016/j.jallcom.2025.178866","DOIUrl":null,"url":null,"abstract":"<div><div>A latent fingerprint (LFP) examination is essential for identifying fingerprints at crime sites, and personal data for legal operations requires economical, eco-friendly, and sensitive new materials. Here, a new composition of intense red-emitting Eu<sup>3+</sup> and Y<sup>3+</sup> co-doped SrTiO<sub>3</sub> perovskites nanophosphor synthesized using a modified sol-gel-assisted combustion technique has been reported. To explore the structural and optical features of the nanophosphors the samples are characterized by various techniques. The powder XRD pattern reveals that the approximate crystallite size is 30 nm, which is consistent with TEM. It is found that with the mid- and near-ultraviolet light excitation, Eu<sup>3+</sup> and Y<sup>3+</sup> co-doped SrTiO<sub>3</sub> nanophosphor displays a strong red emission at 618 nm for optimal concentrations (3 mol% Eu). The CIE (0.656, 0.344), color purity 95 %, CRI 98 %, and CCT values 2435 K, which is less than 5000 K reveals that the Eu<sup>3+</sup> and Y<sup>3+</sup> co-doped SrTiO<sub>3</sub> phosphor was highly useful for the fabrication of warm LED and display device applications. Further, the optimized phosphor was tested (under UV light of 254 nm) for the visualization of LFP and security ink on various material surfaces. The results demonstrated that it provides an effective method for visualizing ridge patterns, offering a promising approach for applications in these areas. Based on the findings, Eu<sup>3+</sup> and Y<sup>3+</sup> co-doped SrTiO<sub>3</sub> show potential for various optoelectronic applications, including WLEDs, LFP detection, security inks, and LEDs.</div></div>","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"1016 ","pages":"Article 178866"},"PeriodicalIF":6.3000,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Impact of Eu3 +/Y3+ doping on the structural and optical properties of SrTiO3 perovskite phosphor and multi-functional applications\",\"authors\":\"Satyam Upadhyay ,&nbsp;Arpita Dwivedi ,&nbsp;Prateek Kumar Yadav ,&nbsp;Monika Srivastava ,&nbsp;Amit Srivastava ,&nbsp;Chandan Upadhyay ,&nbsp;S.K. Srivastava\",\"doi\":\"10.1016/j.jallcom.2025.178866\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A latent fingerprint (LFP) examination is essential for identifying fingerprints at crime sites, and personal data for legal operations requires economical, eco-friendly, and sensitive new materials. Here, a new composition of intense red-emitting Eu<sup>3+</sup> and Y<sup>3+</sup> co-doped SrTiO<sub>3</sub> perovskites nanophosphor synthesized using a modified sol-gel-assisted combustion technique has been reported. To explore the structural and optical features of the nanophosphors the samples are characterized by various techniques. The powder XRD pattern reveals that the approximate crystallite size is 30 nm, which is consistent with TEM. It is found that with the mid- and near-ultraviolet light excitation, Eu<sup>3+</sup> and Y<sup>3+</sup> co-doped SrTiO<sub>3</sub> nanophosphor displays a strong red emission at 618 nm for optimal concentrations (3 mol% Eu). The CIE (0.656, 0.344), color purity 95 %, CRI 98 %, and CCT values 2435 K, which is less than 5000 K reveals that the Eu<sup>3+</sup> and Y<sup>3+</sup> co-doped SrTiO<sub>3</sub> phosphor was highly useful for the fabrication of warm LED and display device applications. Further, the optimized phosphor was tested (under UV light of 254 nm) for the visualization of LFP and security ink on various material surfaces. The results demonstrated that it provides an effective method for visualizing ridge patterns, offering a promising approach for applications in these areas. Based on the findings, Eu<sup>3+</sup> and Y<sup>3+</sup> co-doped SrTiO<sub>3</sub> show potential for various optoelectronic applications, including WLEDs, LFP detection, security inks, and LEDs.</div></div>\",\"PeriodicalId\":344,\"journal\":{\"name\":\"Journal of Alloys and Compounds\",\"volume\":\"1016 \",\"pages\":\"Article 178866\"},\"PeriodicalIF\":6.3000,\"publicationDate\":\"2025-01-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Alloys and Compounds\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0925838825004244\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Alloys and Compounds","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0925838825004244","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

摘要

潜在指纹(LFP)检查是在犯罪现场识别指纹的必要手段,而法律操作所需的个人数据则需要经济、环保、敏感的新材料。本文报道了一种利用溶胶-凝胶辅助燃烧技术合成的Eu3+和Y3+共掺杂SrTiO3钙钛矿纳米磷光体的新组合物。为了探索纳米荧光粉的结构和光学特性,采用各种技术对样品进行了表征。粉末XRD谱图显示晶粒尺寸约为30 nm,与TEM相一致。结果表明,在中紫外光和近紫外光激发下,Eu3+和Y3+共掺杂的SrTiO3纳米荧光粉在最佳浓度(3mol % Eu)为618 nm处表现出较强的红光发射。CIE(0.656, 0.344),色纯度95%,显色指数98%,CCT值2435 K,小于5000 K,表明Eu3+和Y3+共掺杂SrTiO3荧光粉在暖LED和显示器件的制造中非常有用。此外,优化后的荧光粉(在254 nm紫外光下)用于在各种材料表面上显示LFP和安全油墨。结果表明,该方法提供了一种有效的脊图可视化方法,为这些领域的应用提供了一种有前景的方法。基于研究结果,Eu3+和Y3+共掺杂的SrTiO3显示出各种光电应用的潜力,包括wled, LFP检测,安全油墨和led。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Impact of Eu3 +/Y3+ doping on the structural and optical properties of SrTiO3 perovskite phosphor and multi-functional applications

Impact of Eu3 +/Y3+ doping on the structural and optical properties of SrTiO3 perovskite phosphor and multi-functional applications
A latent fingerprint (LFP) examination is essential for identifying fingerprints at crime sites, and personal data for legal operations requires economical, eco-friendly, and sensitive new materials. Here, a new composition of intense red-emitting Eu3+ and Y3+ co-doped SrTiO3 perovskites nanophosphor synthesized using a modified sol-gel-assisted combustion technique has been reported. To explore the structural and optical features of the nanophosphors the samples are characterized by various techniques. The powder XRD pattern reveals that the approximate crystallite size is 30 nm, which is consistent with TEM. It is found that with the mid- and near-ultraviolet light excitation, Eu3+ and Y3+ co-doped SrTiO3 nanophosphor displays a strong red emission at 618 nm for optimal concentrations (3 mol% Eu). The CIE (0.656, 0.344), color purity 95 %, CRI 98 %, and CCT values 2435 K, which is less than 5000 K reveals that the Eu3+ and Y3+ co-doped SrTiO3 phosphor was highly useful for the fabrication of warm LED and display device applications. Further, the optimized phosphor was tested (under UV light of 254 nm) for the visualization of LFP and security ink on various material surfaces. The results demonstrated that it provides an effective method for visualizing ridge patterns, offering a promising approach for applications in these areas. Based on the findings, Eu3+ and Y3+ co-doped SrTiO3 show potential for various optoelectronic applications, including WLEDs, LFP detection, security inks, and LEDs.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Journal of Alloys and Compounds
Journal of Alloys and Compounds 工程技术-材料科学:综合
CiteScore
11.10
自引率
14.50%
发文量
5146
审稿时长
67 days
期刊介绍: The Journal of Alloys and Compounds is intended to serve as an international medium for the publication of work on solid materials comprising compounds as well as alloys. Its great strength lies in the diversity of discipline which it encompasses, drawing together results from materials science, solid-state chemistry and physics.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信