Effect of Temperature on Condensed State Structure and Conductivity Characteristics of Micron-Level Biaxially Oriented Polypropylene Films

Polymer-based dielectric films are increasingly demanded for devices under high electric fields used in new energy vehicles, photovoltaic grid connections, oil and gas exploration, and aerospace. However, leakage current is one of the significant factors limiting the improvement of the insulation performance. This paper tested the leakage current and condensed state structure characteristics of biaxially oriented polypropylene (BOPP) films and obtained the nonlinear characteristics of leakage current of BOPP films in the range of 40–440 V/μm and 40–110 °C. The conduction mechanisms of BOPP films are hopping conductivity within 40–120 V/μm and the Poole–Frenkel effect within 120–440 V/μm, and the threshold electric field of the two kinds conduction mechanisms decreases from 120 to 80 V/μm above 70 °C. The in situ FTIR results indicate that the structure of the BOPP films including band structure, amorphous phase, and isotacticity indices changes above 70 °C, corresponding to the threshold electric field of both conductivity mechanisms gradually decreasing from 120 to 80 V/μm at 70 °C. This study can provide guidance for the optimization design to suppress the leakage current of BOPP and improve its insulation performance.