{"title":"高性能碳捕获用酚醛树脂型微孔有机聚合物。","authors":"Liting Yang, Peiyu Cai, Xuance Jin, Zhengjie Wang, Hong-Cai Zhou, Ning Huang","doi":"10.1002/asia.202401288","DOIUrl":null,"url":null,"abstract":"<p><p>Three new types of Si-centered porous organic polymer (Si-POPs) were successfully prepared using phenolic resin-type chemistry to form C-C bonds. This new family of microporous Si-POPs manifests as uniform, microporous, spherical particles with a high specific surface area. Notably, Si-POPs were engineered to possess varying numbers of hydroxyl (-OH) groups by altering the monomer in the synthetic process. Among these materials, the variant with the highest number of hydroxyl groups exhibited ultra-high CO<sub>2</sub> adsorption capacity, reaching up to 4.3 mmol g<sup>-1</sup> at 273 K and 1.0 bar, which surpasses the performance of most porous polymers. Furthermore, Si-POPs also demonstrated remarkable selectivity adsorption for carbon dioxide over nitrogen (17-50, IAST at 273 K and 1.0 bar). This study not only highlighted the superior CO<sub>2</sub> adsorption properties of Si-POPs but also explored their potential application in selective gas adsorption.</p>","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e202401288"},"PeriodicalIF":3.5000,"publicationDate":"2025-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Phenolic Resin-type Microporous Organic Polymers for High-Performance Carbon Dioxide Adsorption.\",\"authors\":\"Liting Yang, Peiyu Cai, Xuance Jin, Zhengjie Wang, Hong-Cai Zhou, Ning Huang\",\"doi\":\"10.1002/asia.202401288\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Three new types of Si-centered porous organic polymer (Si-POPs) were successfully prepared using phenolic resin-type chemistry to form C-C bonds. This new family of microporous Si-POPs manifests as uniform, microporous, spherical particles with a high specific surface area. Notably, Si-POPs were engineered to possess varying numbers of hydroxyl (-OH) groups by altering the monomer in the synthetic process. Among these materials, the variant with the highest number of hydroxyl groups exhibited ultra-high CO<sub>2</sub> adsorption capacity, reaching up to 4.3 mmol g<sup>-1</sup> at 273 K and 1.0 bar, which surpasses the performance of most porous polymers. Furthermore, Si-POPs also demonstrated remarkable selectivity adsorption for carbon dioxide over nitrogen (17-50, IAST at 273 K and 1.0 bar). This study not only highlighted the superior CO<sub>2</sub> adsorption properties of Si-POPs but also explored their potential application in selective gas adsorption.</p>\",\"PeriodicalId\":145,\"journal\":{\"name\":\"Chemistry - An Asian Journal\",\"volume\":\" \",\"pages\":\"e202401288\"},\"PeriodicalIF\":3.5000,\"publicationDate\":\"2025-01-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry - An Asian Journal\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://doi.org/10.1002/asia.202401288\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry - An Asian Journal","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1002/asia.202401288","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Phenolic Resin-type Microporous Organic Polymers for High-Performance Carbon Dioxide Adsorption.
Three new types of Si-centered porous organic polymer (Si-POPs) were successfully prepared using phenolic resin-type chemistry to form C-C bonds. This new family of microporous Si-POPs manifests as uniform, microporous, spherical particles with a high specific surface area. Notably, Si-POPs were engineered to possess varying numbers of hydroxyl (-OH) groups by altering the monomer in the synthetic process. Among these materials, the variant with the highest number of hydroxyl groups exhibited ultra-high CO2 adsorption capacity, reaching up to 4.3 mmol g-1 at 273 K and 1.0 bar, which surpasses the performance of most porous polymers. Furthermore, Si-POPs also demonstrated remarkable selectivity adsorption for carbon dioxide over nitrogen (17-50, IAST at 273 K and 1.0 bar). This study not only highlighted the superior CO2 adsorption properties of Si-POPs but also explored their potential application in selective gas adsorption.
期刊介绍：
Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics.
Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews.
A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal.
Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).
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