含硒配体的过渡金属配合物用于催化还原、氧化和加氢功能化反应。

IF 3.5 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemistry - An Asian Journal Pub Date : 2025-01-20 DOI:10.1002/asia.202401431

Atul Kumar Maurya, Mohd Farhan Ansari, Saravanakumar Elangovan

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引用次数: 0

摘要

过渡金属介导的催化还原、氧化和加氢官能化反应是重要的有机反应，被认为是高度原子经济的。由于其独特的性质，硒连接的几种过渡金属配合物已被报道用于几种催化应用。本文综述了各种硒负载过渡金属配合物的合成及其在还原、氧化、胺的n -烷基化和加氢官能化反应中的催化应用。此外，我们还比较了各种含有机硒配体的过渡金属配合物的催化活性以及硒被其他含硫元素取代的情况。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Transition Metal Complexes Containing Selenium Ligands for Catalytic Reduction, Oxidation, and Hydrofunctionalization Reactions.

Transition metal-mediated catalytic reduction, oxidation, and hydrofunctionalization reactions are important organic reactions and are considered highly atom-economical. Owing to their unique properties, selenium ligated numerous transition metals-based complexes have been reported for diverse catalytic applications. This review presents the synthesis of various selenium-supported transition metal complexes and their catalytic applications in reduction, oxidation, and hydrofunctionalization reactions. Furthermore, we compare the catalytic activity of various organoselenium ligand-containing transition metal complexes and the replacement of selenium with other chalcogen elements.

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来源期刊

Chemistry - An Asian Journal 化学-化学综合

CiteScore

7.00

自引率

2.40%

发文量

535

审稿时长

1.3 months

期刊介绍： Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics. Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews. A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal. Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).