锆与铪：介孔MOF稳定性的比较研究。

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-01-02 DOI:10.1039/d4cc03103b

Orysia Zaremba , Subhajit Dutta , Jesus Requies , Jacopo Andreo , Stefan Wuttke

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引用次数: 0

摘要

系统地研究了各种介孔Zr和Hf金属有机骨架（mof），即MIP-206， MOF-808和NU-1000，以及微孔UiO-66，并在热稳定性和化学稳定性方面进行了比较。研究了金属类型（Zr vs. Hf）、连接器类型（小而刚性vs.大而柔性）和框架拓扑（2D vs. 3D）对整体框架稳定性的整体影响。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Zirconium vs. hafnium: a comparative study of mesoporous MOF stability†

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Zirconium vs. hafnium: a comparative study of mesoporous MOF stability†

A wide range of mesoporous Zr and Hf metal–organic frameworks (MOFs), namely MIP-206, MOF-808, and NU-1000, as well as the microporous UiO-66, were systematically investigated and compared in terms of thermal and chemical stability. The holistic effects of metal type (Zr vs. Hf), linker type (small and rigid vs. large and flexible), and framework topology (2D vs. 3D) on the overall framework stability were investigated.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.