末端硒化铝和碲化铝的可比合成

IF 2.7 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

New Journal of Chemistry Pub Date : 2024-12-26 DOI:10.1039/D4NJ04255G

Bin Li, Yuanyuan Wang, Sonam Suthar, Manbo Zhang and Kartik Chandra Mondal

引用次数: 0

摘要

β-二酮酸键合Al(I)-化合物(L)Al (L = HC{C（Me)N(Ar)}2, Ar = 2,6- ipr2c6h3）与N-杂环硒脲和碲脲（iPrNHCE）的CE （E = Se, Te）键反应生成[(LAl(iPrNHC)E)] (E = Se, 1；分别为，2)。进行了结构和光谱表征，并对键合细节进行了实验和理论研究。

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Comparable syntheses of terminal aluminum selenide and telluride†

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Comparable syntheses of terminal aluminum selenide and telluride†

The β-diketiminate bonded Al(I)-compound (L)Al (L = HC{C(Me)N(Ar)}₂, Ar = 2,6-iPr₂C₆H₃) reacted with the CE (E = Se, Te) bonds of N-heterocyclic selenourea and tellurourea (^iPrNHCE) to exclusively afford [(LAl(^iPrNHC)E)] (E = Se, 1; Te, 2), respectively. Structural and spectroscopic characterizations were done, and the bonding details were experimentally and theoretically studied.