一种P -亲核试剂阻断了Seyferth - Gilbert反应

IF 2.5 3区化学 Q2 CHEMISTRY, ORGANIC

European Journal of Organic Chemistry Pub Date : 2025-02-24 DOI:10.1002/ejoc.202401286

Yuan‐Jie Wei , Fei‐Long Zhou , Yan Tian , Prof. Dr. Yong‐Feng Cheng

引用次数: 0

摘要

在这里，我们报告了一个中断的Seyferth-Gilbert反应，邻磷酰苯甲醛与Seyferth-Gilbert试剂产生乙烯基膦酸盐。该转化具有显著的化学选择性、温和的反应条件和良好的官能团耐受性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

A P‐nucleophile Interrupted Seyferth‐Gilbert Reaction

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A P‐nucleophile Interrupted Seyferth‐Gilbert Reaction

Herein, we report an interrupted Seyferth–Gilbert reaction of ortho‐phosphanylbenzaldehydes with Seyferth–Gilbert reagent yielding vinylphosphonates. The transformation features remarkable chemoselectivity, mild reaction condition and good functional group tolerance.

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来源期刊

European Journal of Organic Chemistry 化学-有机化学

CiteScore

5.40

自引率

3.60%

发文量

752

审稿时长

1 months

期刊介绍： The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.