Yue Zhao, Dayong Jiang, Man Zhao, Yuanyuan Sun and Haoda Li
{"title":"双通道检测模式氧化锌/有机聚合物/氧化铜异质结双波段光电探测器","authors":"Yue Zhao, Dayong Jiang, Man Zhao, Yuanyuan Sun and Haoda Li","doi":"10.1039/D4TA07692C","DOIUrl":null,"url":null,"abstract":"<p >Most photodetectors (PDs) can only perform optical detection in a fixed response range, and often cannot selectively control the response range, which greatly limits the development of emerging fields such as artificial intelligence, biosensing, optical communication and more. It is still a challenge to integrate dual-band detection and spectral identification into a single device for dual-channel optical detection. In this study, a dual-band PD that was synthesized by deposition of ZnO, organic polymer poly-(<em>N</em>-vinylcarbazole) (PVK) and Cu<small><sub>2</sub></small>O semiconductor materials achieved a breakthrough. It is worth noting that the ZnO/PVK/Cu<small><sub>2</sub></small>O PD can selectively convert the response band between 285–492 nm and 492–645 nm under bias voltage control. The peak responsivity of the PD is 0.19 A W<small><sup>−1</sup></small> at 450 nm under zero-bias conditions, while the peak responsivity is shifted to 556 nm with a peak of 0.20 A W<small><sup>−1</sup></small> at a voltage of −2.5 V under reverse connection. The dual-channel detection of blue and green light can be achieved with simple signal processing, which is closely matched with the emission spectrum of commercially available red, green and blue (RGB) white light emitting diodes (LEDs). This work provides design inspiration for potential applications of dual-band photodetectors in visible light communication, smart sensing devices and other emerging fields in the future.</p>","PeriodicalId":82,"journal":{"name":"Journal of Materials Chemistry A","volume":" 7","pages":" 5315-5323"},"PeriodicalIF":9.5000,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A dual-channel detection mode ZnO/organic polymer/Cu2O heterojunction dual-band photodetector\",\"authors\":\"Yue Zhao, Dayong Jiang, Man Zhao, Yuanyuan Sun and Haoda Li\",\"doi\":\"10.1039/D4TA07692C\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Most photodetectors (PDs) can only perform optical detection in a fixed response range, and often cannot selectively control the response range, which greatly limits the development of emerging fields such as artificial intelligence, biosensing, optical communication and more. It is still a challenge to integrate dual-band detection and spectral identification into a single device for dual-channel optical detection. In this study, a dual-band PD that was synthesized by deposition of ZnO, organic polymer poly-(<em>N</em>-vinylcarbazole) (PVK) and Cu<small><sub>2</sub></small>O semiconductor materials achieved a breakthrough. It is worth noting that the ZnO/PVK/Cu<small><sub>2</sub></small>O PD can selectively convert the response band between 285–492 nm and 492–645 nm under bias voltage control. The peak responsivity of the PD is 0.19 A W<small><sup>−1</sup></small> at 450 nm under zero-bias conditions, while the peak responsivity is shifted to 556 nm with a peak of 0.20 A W<small><sup>−1</sup></small> at a voltage of −2.5 V under reverse connection. The dual-channel detection of blue and green light can be achieved with simple signal processing, which is closely matched with the emission spectrum of commercially available red, green and blue (RGB) white light emitting diodes (LEDs). This work provides design inspiration for potential applications of dual-band photodetectors in visible light communication, smart sensing devices and other emerging fields in the future.</p>\",\"PeriodicalId\":82,\"journal\":{\"name\":\"Journal of Materials Chemistry A\",\"volume\":\" 7\",\"pages\":\" 5315-5323\"},\"PeriodicalIF\":9.5000,\"publicationDate\":\"2025-01-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Chemistry A\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/ta/d4ta07692c\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Chemistry A","FirstCategoryId":"88","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/ta/d4ta07692c","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
大多数光电探测器(pd)只能在固定的响应范围内进行光学检测,往往不能选择性地控制响应范围,这极大地限制了人工智能、生物传感、光通信等新兴领域的发展。将双波段检测和光谱识别集成到单一器件中实现双通道光检测仍然是一个挑战。在本研究中,通过ZnO、有机聚合物聚-(n -乙烯基咔唑)(PVK)和Cu2O半导体材料沉积合成的双波段PD取得了突破。值得注意的是,ZnO/PVK/Cu2O PD在偏压控制下可以选择性地在285 ~ 492 nm和492 ~ 645 nm之间转换响应带。在零偏置条件下,PD在450 nm处的峰值响应度为0.19 A W−1,而在反向连接条件下,PD在- 2.5 V电压下的峰值响应度移至556 nm处,峰值为0.20 A W−1。通过简单的信号处理,可以实现蓝绿光的双通道检测,这与市售的红绿蓝(RGB)白光发光二极管(led)的发射光谱密切匹配。这项工作为未来双波段光电探测器在可见光通信、智能传感器件等新兴领域的潜在应用提供了设计灵感。
A dual-channel detection mode ZnO/organic polymer/Cu2O heterojunction dual-band photodetector
Most photodetectors (PDs) can only perform optical detection in a fixed response range, and often cannot selectively control the response range, which greatly limits the development of emerging fields such as artificial intelligence, biosensing, optical communication and more. It is still a challenge to integrate dual-band detection and spectral identification into a single device for dual-channel optical detection. In this study, a dual-band PD that was synthesized by deposition of ZnO, organic polymer poly-(N-vinylcarbazole) (PVK) and Cu2O semiconductor materials achieved a breakthrough. It is worth noting that the ZnO/PVK/Cu2O PD can selectively convert the response band between 285–492 nm and 492–645 nm under bias voltage control. The peak responsivity of the PD is 0.19 A W−1 at 450 nm under zero-bias conditions, while the peak responsivity is shifted to 556 nm with a peak of 0.20 A W−1 at a voltage of −2.5 V under reverse connection. The dual-channel detection of blue and green light can be achieved with simple signal processing, which is closely matched with the emission spectrum of commercially available red, green and blue (RGB) white light emitting diodes (LEDs). This work provides design inspiration for potential applications of dual-band photodetectors in visible light communication, smart sensing devices and other emerging fields in the future.
期刊介绍:
The Journal of Materials Chemistry A, B & C covers a wide range of high-quality studies in the field of materials chemistry, with each section focusing on specific applications of the materials studied. Journal of Materials Chemistry A emphasizes applications in energy and sustainability, including topics such as artificial photosynthesis, batteries, and fuel cells. Journal of Materials Chemistry B focuses on applications in biology and medicine, while Journal of Materials Chemistry C covers applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry A include catalysis, green/sustainable materials, sensors, and water treatment, among others.