甲基苯胺和卡比多的相互作用：模拟费托合成的一个基本步骤

IF 16.9 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Angewandte Chemie International Edition Pub Date : 2025-01-20 DOI:10.1002/anie.202424699

Dr. Liam K. Burt, Prof. Dr. Anthony F. Hill

引用次数: 0

摘要

通过过渡氢化物-μ-卡比多配合物进行卡比多-氢偶联，得到了异双金属μ-甲基炔配合物[WPt(μ - ch)(CO)2L2(Tp*)]，其中L2 = (PPh3)2, (PPh3)(CO), (dppe), (PPh3)(CNC6H2Me3)，模拟了所提出的费托合成机制的一个基本步骤。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

The Interplay of Methylidyne and Carbido Species: Modeling a Fundamental Step in the Fischer–Tropsch Synthesis

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The Interplay of Methylidyne and Carbido Species: Modeling a Fundamental Step in the Fischer–Tropsch Synthesis

Heterobimetallic μ-methylidyne complexes [WPt(μ₂-CH)(CO)₂L₂(Tp*)], where L₂=(PPh₃)₂, (PPh₃)(CO), (dppe), (PPh₃)(CNC₆H₂Me₃), have been obtained via the intermediacy of transient hydrido-μ-carbido complexes that undergo carbido-hydrido coupling to model a fundamental step in the proposed mechanism for Fischer–Tropsch synthesis.

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来源期刊

Angewandte Chemie International Edition 化学-化学综合

CiteScore

26.60

自引率

6.60%

发文量

3549

审稿时长

1.5 months

期刊介绍： Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.