{"title":"线性氰基桥接多金属配合物分子设计的最新进展和挑战","authors":"Jin-Hui Fu, Bing-Chang Tan, Ying Song, Zi-Hang Wu, Xin-Tao Wu and Tian-Lu Sheng","doi":"10.1039/D4DT03028A","DOIUrl":null,"url":null,"abstract":"<p >Cyanido-bridged multimetallic complexes have been extensively studied for their potential applications in molecular electronics and spintronics. The design of these complexes involves the strategic placement of metal centers and the use of cyanide bridges to facilitate electron transfer between metal ions. The challenges in this field include the precise control of the electronic states and the stability of the complexes under various conditions. Researchers are exploring new synthetic methods and functionalization strategies to overcome these challenges and to enhance the performance of these complexes in practical applications. Overall, this review demonstrates the design of linear cyanido-bridged multimetallic complexes and related electronic properties, emphasizing the remaining challenges.</p>","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":" 11","pages":" 4396-4404"},"PeriodicalIF":3.3000,"publicationDate":"2025-01-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Recent developments and challenges of molecular design in linear cyanido-bridged multimetallic complexes\",\"authors\":\"Jin-Hui Fu, Bing-Chang Tan, Ying Song, Zi-Hang Wu, Xin-Tao Wu and Tian-Lu Sheng\",\"doi\":\"10.1039/D4DT03028A\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Cyanido-bridged multimetallic complexes have been extensively studied for their potential applications in molecular electronics and spintronics. The design of these complexes involves the strategic placement of metal centers and the use of cyanide bridges to facilitate electron transfer between metal ions. The challenges in this field include the precise control of the electronic states and the stability of the complexes under various conditions. Researchers are exploring new synthetic methods and functionalization strategies to overcome these challenges and to enhance the performance of these complexes in practical applications. Overall, this review demonstrates the design of linear cyanido-bridged multimetallic complexes and related electronic properties, emphasizing the remaining challenges.</p>\",\"PeriodicalId\":71,\"journal\":{\"name\":\"Dalton Transactions\",\"volume\":\" 11\",\"pages\":\" 4396-4404\"},\"PeriodicalIF\":3.3000,\"publicationDate\":\"2025-01-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Dalton Transactions\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/dt/d4dt03028a\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dalton Transactions","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/dt/d4dt03028a","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Recent developments and challenges of molecular design in linear cyanido-bridged multimetallic complexes
Cyanido-bridged multimetallic complexes have been extensively studied for their potential applications in molecular electronics and spintronics. The design of these complexes involves the strategic placement of metal centers and the use of cyanide bridges to facilitate electron transfer between metal ions. The challenges in this field include the precise control of the electronic states and the stability of the complexes under various conditions. Researchers are exploring new synthetic methods and functionalization strategies to overcome these challenges and to enhance the performance of these complexes in practical applications. Overall, this review demonstrates the design of linear cyanido-bridged multimetallic complexes and related electronic properties, emphasizing the remaining challenges.
期刊介绍:
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.