用于4-硝基甲苯电化学检测的钒酸铒纳米带的简易合成

IF 5.8 2区 环境科学与生态学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Aravind Radha, Sea-Fue Wang
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引用次数: 0

摘要

在这项工作中,利用简单的水热法制备ErVO4纳米颗粒。将制备的ErVO4纳米粒子用于4-硝基甲苯中有害有机污染物的电化学检测。利用各种表征技术,包括x射线衍射、场发射扫描电子显微镜和高分辨率透射电子显微镜,研究了ErVO4纳米颗粒的物理化学性质。采用差分脉冲伏安法(DPV)和循环伏安法(CV)对4-硝基甲苯进行了电化学检测。在0.01 ~ 375 μM的检测范围内,ErVO4修饰的丝网印刷碳电极(SPCE)传感器具有良好的线性响应,检测限低至9 nM。构建的ErVO4/SPCE传感器在其他化学物质存在下具有选择性检测,重现性、可重复使用性和真实样品验证,回收率为(±95.00-99.00%)。与之前报道的几种传感器相比,ErVO4的4-硝基甲苯检测的LOD要低得多,而且制造起来更容易、更快。所述的ervo4修饰的4-硝基甲苯电化学传感器价格合理且灵活,可实现对成功的环境监测和水质认证至关重要的4-硝基甲苯即时检测。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Facile synthesis of erbium vanadate nanoribbons for electrochemical detection of 4-nitrotoluene
In this work, utilizes a simple hydrothermal process for preparing ErVO4 nanoparticles. The prepared ErVO4 nanoparticles were used for the electrochemical detection of hazardous organic contaminants in 4-nitrotoluene. The physicochemical properties of ErVO4 nanoparticles were examined using various characterization techniques, including X-ray diffraction, field emission scanning electron microscopy, and high-resolution transmission electron microscopy. Using differential pulse voltammetry (DPV) and cyclic voltammetry (CV), the electrochemical detection of 4-nitrotoluene was assessed. In the 0.01-375 μM detection ranges, the ErVO4 modified screen-printed carbon electrode (SPCE) sensor showed a linear response and a low detection limit of 9 nM. The constructed ErVO4/SPCE sensor exhibits selective detection in the presence of other chemical species, reproducibility, reusability, and real sample validation with a recovery range of (±95.00–99.00%). Compared to several previously reported sensors, the ErVO4 gave a substantially lower LOD for 4-nitrotoluene detection and was easier and faster to fabricate. The proposed ErVO4-modified electrochemical sensor for 4-nitrotoluene described is affordable and flexible, enabling point-of-care 4-nitrotoluene testing essential for successful environmental monitoring and water quality accreditation.
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来源期刊
Environmental Science: Nano
Environmental Science: Nano CHEMISTRY, MULTIDISCIPLINARY-ENVIRONMENTAL SCIENCES
CiteScore
12.20
自引率
5.50%
发文量
290
审稿时长
2.1 months
期刊介绍: Environmental Science: Nano serves as a comprehensive and high-impact peer-reviewed source of information on the design and demonstration of engineered nanomaterials for environment-based applications. It also covers the interactions between engineered, natural, and incidental nanomaterials with biological and environmental systems. This scope includes, but is not limited to, the following topic areas: Novel nanomaterial-based applications for water, air, soil, food, and energy sustainability Nanomaterial interactions with biological systems and nanotoxicology Environmental fate, reactivity, and transformations of nanoscale materials Nanoscale processes in the environment Sustainable nanotechnology including rational nanomaterial design, life cycle assessment, risk/benefit analysis
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