Huda I. Ahemad, Ganesh E. Patil, Sarika D. Shinde, Dnyaneshwari Y. Patil, Gotan H. Jain, D. D. Kajale, S. R. Gadakh, Sharad B. Patil
{"title":"硫酸铜单晶的合成与表征","authors":"Huda I. Ahemad, Ganesh E. Patil, Sarika D. Shinde, Dnyaneshwari Y. Patil, Gotan H. Jain, D. D. Kajale, S. R. Gadakh, Sharad B. Patil","doi":"10.1134/S1063783424601504","DOIUrl":null,"url":null,"abstract":"<p>In this study, copper sulfate pentahydrate (CuSO<sub>4</sub>·5H<sub>2</sub>O) single crystals, measuring up to 8 × 8 × 2 cm, were successfully grown using the hot plate technique. The synthesized crystals were characterized using several analytical methods, including X-ray diffraction (XRD), UV-visible spectroscopy, Brunauer–Emmett–Teller (BET) surface area analysis, and cyclic voltammetry (CV). XRD analysis confirmed that the crystals possess a triclinic structure. Optical property assessments revealed broad transparency in the visible spectrum, with a band gap (<i>E</i><sub>g</sub>) of 4.02 eV as determined by UV-visible spectroscopy. BET analysis showed a surface area of 1.015 cm<sup>2</sup>/g and a pore volume of 0.0025 cm<sup>3</sup>/g. Additionally, etching experiments were performed over varying durations to preserve the crystal structure and investigate surface behavior. These findings provide valuable insights into both the growth and properties of CuSO<sub>4</sub>·5H<sub>2</sub>O crystals, suggesting their potential applications in various scientific fields.</p>","PeriodicalId":731,"journal":{"name":"Physics of the Solid State","volume":"66 12","pages":"642 - 652"},"PeriodicalIF":0.9000,"publicationDate":"2025-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Characterization of Copper Sulfate Single Crystals\",\"authors\":\"Huda I. Ahemad, Ganesh E. Patil, Sarika D. Shinde, Dnyaneshwari Y. Patil, Gotan H. Jain, D. D. Kajale, S. R. Gadakh, Sharad B. Patil\",\"doi\":\"10.1134/S1063783424601504\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In this study, copper sulfate pentahydrate (CuSO<sub>4</sub>·5H<sub>2</sub>O) single crystals, measuring up to 8 × 8 × 2 cm, were successfully grown using the hot plate technique. The synthesized crystals were characterized using several analytical methods, including X-ray diffraction (XRD), UV-visible spectroscopy, Brunauer–Emmett–Teller (BET) surface area analysis, and cyclic voltammetry (CV). XRD analysis confirmed that the crystals possess a triclinic structure. Optical property assessments revealed broad transparency in the visible spectrum, with a band gap (<i>E</i><sub>g</sub>) of 4.02 eV as determined by UV-visible spectroscopy. BET analysis showed a surface area of 1.015 cm<sup>2</sup>/g and a pore volume of 0.0025 cm<sup>3</sup>/g. Additionally, etching experiments were performed over varying durations to preserve the crystal structure and investigate surface behavior. These findings provide valuable insights into both the growth and properties of CuSO<sub>4</sub>·5H<sub>2</sub>O crystals, suggesting their potential applications in various scientific fields.</p>\",\"PeriodicalId\":731,\"journal\":{\"name\":\"Physics of the Solid State\",\"volume\":\"66 12\",\"pages\":\"642 - 652\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2025-01-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Physics of the Solid State\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1063783424601504\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, CONDENSED MATTER\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physics of the Solid State","FirstCategoryId":"101","ListUrlMain":"https://link.springer.com/article/10.1134/S1063783424601504","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, CONDENSED MATTER","Score":null,"Total":0}
Synthesis and Characterization of Copper Sulfate Single Crystals
In this study, copper sulfate pentahydrate (CuSO4·5H2O) single crystals, measuring up to 8 × 8 × 2 cm, were successfully grown using the hot plate technique. The synthesized crystals were characterized using several analytical methods, including X-ray diffraction (XRD), UV-visible spectroscopy, Brunauer–Emmett–Teller (BET) surface area analysis, and cyclic voltammetry (CV). XRD analysis confirmed that the crystals possess a triclinic structure. Optical property assessments revealed broad transparency in the visible spectrum, with a band gap (Eg) of 4.02 eV as determined by UV-visible spectroscopy. BET analysis showed a surface area of 1.015 cm2/g and a pore volume of 0.0025 cm3/g. Additionally, etching experiments were performed over varying durations to preserve the crystal structure and investigate surface behavior. These findings provide valuable insights into both the growth and properties of CuSO4·5H2O crystals, suggesting their potential applications in various scientific fields.
期刊介绍：
Presents the latest results from Russia’s leading researchers in condensed matter physics at the Russian Academy of Sciences and other prestigious institutions. Covers all areas of solid state physics including solid state optics, solid state acoustics, electronic and vibrational spectra, phase transitions, ferroelectricity, magnetism, and superconductivity. Also presents review papers on the most important problems in solid state physics.
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