可理解的量子动力学:从作用的量子到热力学第二定律

IF 2.8 3区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY
Arto Annila
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引用次数: 0

摘要

热力学第二定律是从最小作用原理推导出来的,它假定作用的量子是万物不可分割、不可摧毁的基本组成部分。在它们达到平衡的最短时间路径上,量子从系统移动到它的周围环境,反之亦然,这样动能、势能和耗散的能量就一致了。当以对数形式重新表示时,这种自由能减少的更可能状态的电流等于熵增加的原理,热力学第二定律,包括与路径无关的动态和路径相关的几何相移。尽管是精确的,但进化到熵最大值(相当于自由能最小值)的方程无法求解,因为进化消耗了它自己的驱动力,变得依赖于路径。因此,未来在自由能的范围内仍然是开放的。如前所述,从开放量子系统的统计物理中导出的熵和能量上可区分的状态;而玻尔兹曼熵则列举了能量上无法区分的微观状态。因此,开放系统的统计物理不同于封闭系统的统计物理:状态空间中向热力学平衡的不可逆演化与相空间中可想象的构型之间的稳态旋转形成对比。这种具体的理解解释了,除其他外,增加的无序不是自然规律本身,而是在最短时间内与不连贯的环境达到平衡的规律的结果。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Comprehensible dynamics of quanta: from the quantum of action to the 2nd law of thermodynamics

The 2nd law of thermodynamics is derived from the principle of least action, positing that the quantum of action is the indivisible and indestructible basic building block of everything. On their least-time paths to balance, the quanta move from the system to its surroundings, or vice versa, so that the kinetic, potential, and dissipated energy tally. When re-expressed in logarithmic terms, this current toward more probable states with decreasing free energy equates to the principle of increasing entropy, the 2nd law of thermodynamics, including path-independent dynamic and path dependent geometric phase shifts. Despite being exact, the equation of evolution to entropy maximum, equivalent to free energy minimum, cannot be solved because evolution, consuming its own driving forces, becomes path dependent. Thus, the future remains open within free energy bounds. As discussed, the entropy derived from the statistical physics of open quantum systems sums states distinguishable in energy; whereas, Boltzmann’s entropy enumerates microstates indistinguishable in energy. Consequently, the statistical physics of open systems differs from that of closed systems: The irreversible evolution in the state space toward thermodynamic balance contrasts with the steady-state revolution in phase space between conceivable configurations. This concrete comprehension explains, among other things, that increasing disorder is not a law of nature itself but a consequence of the law to attain balance with incoherent surroundings in the least time.

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来源期刊
The European Physical Journal Plus
The European Physical Journal Plus PHYSICS, MULTIDISCIPLINARY-
CiteScore
5.40
自引率
8.80%
发文量
1150
审稿时长
4-8 weeks
期刊介绍: The aims of this peer-reviewed online journal are to distribute and archive all relevant material required to document, assess, validate and reconstruct in detail the body of knowledge in the physical and related sciences. The scope of EPJ Plus encompasses a broad landscape of fields and disciplines in the physical and related sciences - such as covered by the topical EPJ journals and with the explicit addition of geophysics, astrophysics, general relativity and cosmology, mathematical and quantum physics, classical and fluid mechanics, accelerator and medical physics, as well as physics techniques applied to any other topics, including energy, environment and cultural heritage.
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