以准芳香族螯合物为中心的自由基：制备、反应性及应用前景

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2025-01-14 DOI:10.1007/s11172-024-4433-1

A. S. Chuprin

引用次数: 0

摘要

综述了以螯合物为中心的自由基（螯合物前体自由基反应的大环产物）的主要合成策略和最佳制备方法。分析了该类化合物作为自由基聚合引发剂和顺磁探针在MRI和EPR研究中的实际应用前景。

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Quasi-aromatic clathrochelate-centered radicals: preparation, reactivity, and prospects for practical application

The review is devoted to the main synthetic strategies and optimal methods for preparation of persistent clathrochelate-centered radicals, the macrobicyclic products of free-radical reactions of the clathrochelate precursors. Prospects for practical applications of this type of compounds as radical polymerization initiators and paramagnetic probes for MRI and EPR studies are analyzed.

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.