一种具有混合电子给体和电子受体配体的金属有机骨架，用于高效锂离子存储。

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-01-07 DOI:10.1039/d4cc05567e

Ruo-Nan Wang , Yu-Chuan Tan , Wei Liu , Zi-Yi Wang , Jun-Die Zhang , Qin-Yu Zhu

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引用次数: 0

摘要

利用电子供体四噻富戊二烯（TTF）和电子受体萘二亚胺（NDI）衍生物合成了三维 Zn-TTF/NDI-MOF。多个氧化还原活性位点和电荷转移赋予了原始 MOF 阳极出色的速率行为和长期循环性能（在 1 A g-1 的条件下，600 次循环的平均比容量为 956 mA h g-1）。这项研究凸显了精心设计的 MOFs 在开发高效阳极材料方面的巨大潜力。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

A metal–organic framework with mixed electron donor and electron acceptor ligands for efficient lithium-ion storage†

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A metal–organic framework with mixed electron donor and electron acceptor ligands for efficient lithium-ion storage†

Electron donor tetrathiafulvalene (TTF) and electron acceptor naphthalene diimide (NDI) derivatives were used to synthesize a 3D Zn-TTF/NDI-MOF. Multiple redox active sites and charge transfer endow the pristine MOF anode with excellent rate behavior and long term cycling performance (with an average specific capacity of 956 mA h g⁻¹ at 1 A g⁻¹ over 600 cycles). This study highlights the great potential of elaborately-designed MOFs for developing efficient anode materials.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.