{"title":"Suzuki Miyaura反应中纳米催化剂的绿色介质","authors":"Sharda Pasricha , Sachidanand , Abhay Srivastava , Srishti Yadav , Ann Sunny , Nikita Tuwani , T.M. Rangarajan , Kavita Mittal","doi":"10.1016/j.ccr.2025.216431","DOIUrl":null,"url":null,"abstract":"<div><div>The exponential growth pertaining to the Suzuki–Miyaura(SM) reaction and its appliances in the last decade speaks volumes about its efficiency and effectiveness in the production of pharmaceuticals, polymers, materials, fine chemicals, and the total synthesis of natural products. The usage of less toxic, biocompatible, and common coinage metal catalysts; the deployment of supported catalysts and nano catalysts; the involvement of less toxic electrophilic partners; employment of biocompatible supports, and greener reaction media are prominent strategies for greener and sustainable SM reaction. Given the advantages for industry, the environment, and the public, and since solvents are used in larger quantities during organic synthesis, which contributes to a huge impact on the environment and health, a thorough grasp of the numerous greener approaches focused on a variety of newer supported nano catalytic systems and benign media for SM reaction need to be explored further. This review encompasses research published between 2020 and 2024, that discusses SM reaction with effectually supported nano catalysts in a range of greener reaction media.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"528 ","pages":"Article 216431"},"PeriodicalIF":20.3000,"publicationDate":"2025-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Greener media for nano catalysts in Suzuki Miyaura reaction\",\"authors\":\"Sharda Pasricha , Sachidanand , Abhay Srivastava , Srishti Yadav , Ann Sunny , Nikita Tuwani , T.M. Rangarajan , Kavita Mittal\",\"doi\":\"10.1016/j.ccr.2025.216431\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The exponential growth pertaining to the Suzuki–Miyaura(SM) reaction and its appliances in the last decade speaks volumes about its efficiency and effectiveness in the production of pharmaceuticals, polymers, materials, fine chemicals, and the total synthesis of natural products. The usage of less toxic, biocompatible, and common coinage metal catalysts; the deployment of supported catalysts and nano catalysts; the involvement of less toxic electrophilic partners; employment of biocompatible supports, and greener reaction media are prominent strategies for greener and sustainable SM reaction. Given the advantages for industry, the environment, and the public, and since solvents are used in larger quantities during organic synthesis, which contributes to a huge impact on the environment and health, a thorough grasp of the numerous greener approaches focused on a variety of newer supported nano catalytic systems and benign media for SM reaction need to be explored further. This review encompasses research published between 2020 and 2024, that discusses SM reaction with effectually supported nano catalysts in a range of greener reaction media.</div></div>\",\"PeriodicalId\":289,\"journal\":{\"name\":\"Coordination Chemistry Reviews\",\"volume\":\"528 \",\"pages\":\"Article 216431\"},\"PeriodicalIF\":20.3000,\"publicationDate\":\"2025-01-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Coordination Chemistry Reviews\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0010854525000013\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Coordination Chemistry Reviews","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010854525000013","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Greener media for nano catalysts in Suzuki Miyaura reaction
The exponential growth pertaining to the Suzuki–Miyaura(SM) reaction and its appliances in the last decade speaks volumes about its efficiency and effectiveness in the production of pharmaceuticals, polymers, materials, fine chemicals, and the total synthesis of natural products. The usage of less toxic, biocompatible, and common coinage metal catalysts; the deployment of supported catalysts and nano catalysts; the involvement of less toxic electrophilic partners; employment of biocompatible supports, and greener reaction media are prominent strategies for greener and sustainable SM reaction. Given the advantages for industry, the environment, and the public, and since solvents are used in larger quantities during organic synthesis, which contributes to a huge impact on the environment and health, a thorough grasp of the numerous greener approaches focused on a variety of newer supported nano catalytic systems and benign media for SM reaction need to be explored further. This review encompasses research published between 2020 and 2024, that discusses SM reaction with effectually supported nano catalysts in a range of greener reaction media.
期刊介绍:
Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers.
The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.