山茱萸的二萜化学空间。地上部分

IF 4.8 3区 化学 Q1 CHEMISTRY, MEDICINAL
Gabin T. M. Bitchagno, Nathan Reynolds, Monique S. J. Simmonds
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引用次数: 0

摘要

Plectranthinae分支,包括Plectranthus, Ocimum和Aeollanthus等属,以其多样化的二萜类化合物而闻名。虽然许多研究加深了对整个进化支系二萜多样性的理解,但Aeollanthus物种仍然未被充分探索,只有两项研究关注它们的二萜谱。石质和多肉植物山竹叶提取物的核磁共振化学分析。揭示了一系列具有异吡烷和阿比烷骨架的二萜,包括一些以前未报道的类似物。有趣的是,分离的化合物通过检查其MS2光谱中的产物离子,提供了对这两类二萜的分解模式的见解。这些数据为评价该物种在该分支中相对于其他物种的分类位置提供了有价值的信息。图形抽象
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Diterpene chemical space of Aeollanthus buchnerianus Briq. aerial part

The Plectranthinae clade, which includes genera such as Plectranthus, Ocimum, and Aeollanthus, is well known for its diverse array of diterpenoids. While numerous studies have deepened the understanding of diterpene diversity across the clade, Aeollanthus species remain underexplored, with only two studies focusing on their diterpene profiles. The NMR-based chemical profiling of the EtOAc leaf extract of the rocky and succulent species Aeollanthus buchnerianus Briq. reveals a range of diterpenes with isopimarane and abietane skeletons including several previously unreported analogues. Interestingly, the isolated compounds provided insights into the breakdown patterns of both diterpene classes by examining the product ions in their MS2 spectra. These data offer valuable information for evaluating the taxonomic position of this species in relation to other species within the clade.

Graphical Abstract

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来源期刊
Natural Products and Bioprospecting
Natural Products and Bioprospecting CHEMISTRY, MEDICINAL-
CiteScore
8.30
自引率
2.10%
发文量
39
审稿时长
13 weeks
期刊介绍: Natural Products and Bioprospecting serves as an international forum for essential research on natural products and focuses on, but is not limited to, the following aspects: Natural products: isolation and structure elucidation Natural products: synthesis Biological evaluation of biologically active natural products Bioorganic and medicinal chemistry Biosynthesis and microbiological transformation Fermentation and plant tissue cultures Bioprospecting of natural products from natural resources All research articles published in this journal have undergone rigorous peer review. In addition to original research articles, Natural Products and Bioprospecting publishes reviews and short communications, aiming to rapidly disseminate the research results of timely interest, and comprehensive reviews of emerging topics in all the areas of natural products. It is also an open access journal, which provides free access to its articles to anyone, anywhere.
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