评估苯、甲苯和二甲苯(BTX)的光降解效率:使用活性炭(AC)、沸石咪唑酸框架-8 (ZIF-8)和金属锆-有机框架(Zr-MOF)进行比较研究。

IF 2.5 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL
Water Science and Technology Pub Date : 2024-12-01 Epub Date: 2024-11-25 DOI:10.2166/wst.2024.385
Shibyendu Nikhar, Mitun Chakraborty
{"title":"评估苯、甲苯和二甲苯(BTX)的光降解效率:使用活性炭(AC)、沸石咪唑酸框架-8 (ZIF-8)和金属锆-有机框架(Zr-MOF)进行比较研究。","authors":"Shibyendu Nikhar, Mitun Chakraborty","doi":"10.2166/wst.2024.385","DOIUrl":null,"url":null,"abstract":"<p><p>In this study, three different materials were investigated for their ability to degrade benzene, toluene, and xylene (BTX) using light energy. The materials studied were activated charcoal (AC), zeolitic imidazolate framework (ZIF-8), and zirconium metal-organic framework (Zr-MOF). Initially, AC, ZIF-8, and Zr-MOF were characterized using X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) surface area analysis, and spectroscopic analysis techniques. Based on their excellent features, that is, band gap (5.5, 5.45, and 4.75 eV), surface area (711.5, 1,122.1, and 535.4 m<sup>2</sup>/g), and pore volume (0.291, 0.369, and 0.628 cm<sup>3</sup>/g), a comparative photodegradation analysis of BTX was performed in acetonitrile. We found that Zr-MOF is the best photocatalyst to degrade BTX, with degradation percentages of 97, 95, and 94% (B > T > X), respectively, followed by ZIF-8 and AC. Our study suggests that these photocatalysts can be used to degrade BTX using light energy, which could reduce the health and environmental impacts of BTX. Our results illustrate that advanced porous materials may be established as photocatalyst materials with the potential to address the long-standing challenges associated with pollutant degradation.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"90 12","pages":"3193-3209"},"PeriodicalIF":2.5000,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Assessing the photodegradation efficiency of benzene, toluene, and xylene (BTX): A comparative investigation using activated charcoal (AC), zeolitic imidazolate framework-8 (ZIF-8), and zirconium metal-organic framework (Zr-MOF).\",\"authors\":\"Shibyendu Nikhar, Mitun Chakraborty\",\"doi\":\"10.2166/wst.2024.385\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>In this study, three different materials were investigated for their ability to degrade benzene, toluene, and xylene (BTX) using light energy. The materials studied were activated charcoal (AC), zeolitic imidazolate framework (ZIF-8), and zirconium metal-organic framework (Zr-MOF). Initially, AC, ZIF-8, and Zr-MOF were characterized using X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) surface area analysis, and spectroscopic analysis techniques. Based on their excellent features, that is, band gap (5.5, 5.45, and 4.75 eV), surface area (711.5, 1,122.1, and 535.4 m<sup>2</sup>/g), and pore volume (0.291, 0.369, and 0.628 cm<sup>3</sup>/g), a comparative photodegradation analysis of BTX was performed in acetonitrile. We found that Zr-MOF is the best photocatalyst to degrade BTX, with degradation percentages of 97, 95, and 94% (B > T > X), respectively, followed by ZIF-8 and AC. Our study suggests that these photocatalysts can be used to degrade BTX using light energy, which could reduce the health and environmental impacts of BTX. Our results illustrate that advanced porous materials may be established as photocatalyst materials with the potential to address the long-standing challenges associated with pollutant degradation.</p>\",\"PeriodicalId\":23653,\"journal\":{\"name\":\"Water Science and Technology\",\"volume\":\"90 12\",\"pages\":\"3193-3209\"},\"PeriodicalIF\":2.5000,\"publicationDate\":\"2024-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Water Science and Technology\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://doi.org/10.2166/wst.2024.385\",\"RegionNum\":4,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/11/25 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q3\",\"JCRName\":\"ENGINEERING, ENVIRONMENTAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Water Science and Technology","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.2166/wst.2024.385","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/11/25 0:00:00","PubModel":"Epub","JCR":"Q3","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
引用次数: 0

摘要

在这项研究中,研究了三种不同的材料利用光能降解苯、甲苯和二甲苯(BTX)的能力。研究的材料有活性炭(AC)、沸石咪唑酸骨架(ZIF-8)和金属锆-有机骨架(Zr-MOF)。首先,利用x射线衍射(XRD)、傅里叶变换红外(FTIR)光谱、扫描电子显微镜(SEM)、布鲁诺尔-埃米特-泰勒(BET)表面积分析和光谱分析技术对AC、ZIF-8和Zr-MOF进行了表征。基于其优异的带隙(5.5、5.45和4.75 eV)、比表面积(711.5、1,122.1和535.4 m2/g)和孔体积(0.291、0.369和0.628 cm3/g)特性,在乙腈中进行了比较光降解分析。我们发现Zr-MOF是降解BTX的最佳光催化剂,降解率分别为97%、95%和94% (b> T > X),其次是ZIF-8和AC。我们的研究表明,这些光催化剂可以利用光能降解BTX,从而减少BTX对健康和环境的影响。我们的研究结果表明,先进的多孔材料可以作为光催化剂材料,具有解决与污染物降解相关的长期挑战的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Assessing the photodegradation efficiency of benzene, toluene, and xylene (BTX): A comparative investigation using activated charcoal (AC), zeolitic imidazolate framework-8 (ZIF-8), and zirconium metal-organic framework (Zr-MOF).

In this study, three different materials were investigated for their ability to degrade benzene, toluene, and xylene (BTX) using light energy. The materials studied were activated charcoal (AC), zeolitic imidazolate framework (ZIF-8), and zirconium metal-organic framework (Zr-MOF). Initially, AC, ZIF-8, and Zr-MOF were characterized using X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) surface area analysis, and spectroscopic analysis techniques. Based on their excellent features, that is, band gap (5.5, 5.45, and 4.75 eV), surface area (711.5, 1,122.1, and 535.4 m2/g), and pore volume (0.291, 0.369, and 0.628 cm3/g), a comparative photodegradation analysis of BTX was performed in acetonitrile. We found that Zr-MOF is the best photocatalyst to degrade BTX, with degradation percentages of 97, 95, and 94% (B > T > X), respectively, followed by ZIF-8 and AC. Our study suggests that these photocatalysts can be used to degrade BTX using light energy, which could reduce the health and environmental impacts of BTX. Our results illustrate that advanced porous materials may be established as photocatalyst materials with the potential to address the long-standing challenges associated with pollutant degradation.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Water Science and Technology
Water Science and Technology 环境科学-工程:环境
CiteScore
4.90
自引率
3.70%
发文量
366
审稿时长
4.4 months
期刊介绍: Water Science and Technology publishes peer-reviewed papers on all aspects of the science and technology of water and wastewater. Papers are selected by a rigorous peer review procedure with the aim of rapid and wide dissemination of research results, development and application of new techniques, and related managerial and policy issues. Scientists, engineers, consultants, managers and policy-makers will find this journal essential as a permanent record of progress of research activities and their practical applications.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信