{"title":"浸没式超滤膜的污染和化学清洗策略:同步的实验规模、全尺寸和工程测试。","authors":"Xiwang Zhu, Chengyue Fan, Yichen Fang, Wenqing Yu, Yawei Xie, Hongyuan Liu","doi":"10.3390/membranes14120251","DOIUrl":null,"url":null,"abstract":"<p><p>This study investigated membrane fouling issues associated with the operation of a submerged ultrafiltration membrane in a drinking water treatment plant (DWTP) and optimized the associated chemical cleaning strategies. By analyzing the surface components of the membrane foulant and the compositions of the membrane cleaning solution, the primary causes of membrane fouling were identified. Membrane fouling control strategies suitable for the DWTP were evaluated through chemical cleaning tests conducted for bench-scale, full-scale, and engineering cases. The results show that the membrane foulants were primarily composed of a mixture of inorganics and organics; the inorganics were mainly composed of Al and Si, while the organics were primarily humic acid (HA). Sodium citrate proved to be the most effective cleaning agent for inorganic fouling, which was mainly composed of Al, whereas sodium hypochlorite (NaClO) combined with sodium hydroxide (NaOH) showed the best removal efficiency for organic fouling, which predominantly consisted of HA and Si. However, sodium hypochlorite (NaClO) combined with sodium hydroxide (NaOH) showed the best removal efficiency for organic fouling and Si; organic fouling predominantly consisted of HA. Based on the bench-scale test results, flux recovery was verified in the full-scale system. Under a constant pressure of 30 kPa, the combined acid-alkali cleaning achieved the best flux recovery, restoring the flux from 22.8 L/(m<sup>2</sup>·h) to 66.75 L/(m<sup>2</sup>·h). In the engineering tests, combined acid-alkali cleaning yielded results consistent with those of the full-scale tests. In the practical engineering cleaning process, adopting a cleaning strategy of alkaline (NaClO + NaOH) cleaning followed by acidic (sodium citrate) cleaning can effectively solve the membrane fouling problem.</p>","PeriodicalId":18410,"journal":{"name":"Membranes","volume":"14 12","pages":""},"PeriodicalIF":3.3000,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11679730/pdf/","citationCount":"0","resultStr":"{\"title\":\"Fouling and Chemical Cleaning Strategies for Submerged Ultrafiltration Membrane: Synchronized Bench-Scale, Full-Scale, and Engineering Tests.\",\"authors\":\"Xiwang Zhu, Chengyue Fan, Yichen Fang, Wenqing Yu, Yawei Xie, Hongyuan Liu\",\"doi\":\"10.3390/membranes14120251\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>This study investigated membrane fouling issues associated with the operation of a submerged ultrafiltration membrane in a drinking water treatment plant (DWTP) and optimized the associated chemical cleaning strategies. By analyzing the surface components of the membrane foulant and the compositions of the membrane cleaning solution, the primary causes of membrane fouling were identified. Membrane fouling control strategies suitable for the DWTP were evaluated through chemical cleaning tests conducted for bench-scale, full-scale, and engineering cases. The results show that the membrane foulants were primarily composed of a mixture of inorganics and organics; the inorganics were mainly composed of Al and Si, while the organics were primarily humic acid (HA). Sodium citrate proved to be the most effective cleaning agent for inorganic fouling, which was mainly composed of Al, whereas sodium hypochlorite (NaClO) combined with sodium hydroxide (NaOH) showed the best removal efficiency for organic fouling, which predominantly consisted of HA and Si. However, sodium hypochlorite (NaClO) combined with sodium hydroxide (NaOH) showed the best removal efficiency for organic fouling and Si; organic fouling predominantly consisted of HA. Based on the bench-scale test results, flux recovery was verified in the full-scale system. Under a constant pressure of 30 kPa, the combined acid-alkali cleaning achieved the best flux recovery, restoring the flux from 22.8 L/(m<sup>2</sup>·h) to 66.75 L/(m<sup>2</sup>·h). In the engineering tests, combined acid-alkali cleaning yielded results consistent with those of the full-scale tests. In the practical engineering cleaning process, adopting a cleaning strategy of alkaline (NaClO + NaOH) cleaning followed by acidic (sodium citrate) cleaning can effectively solve the membrane fouling problem.</p>\",\"PeriodicalId\":18410,\"journal\":{\"name\":\"Membranes\",\"volume\":\"14 12\",\"pages\":\"\"},\"PeriodicalIF\":3.3000,\"publicationDate\":\"2024-11-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11679730/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Membranes\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.3390/membranes14120251\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Membranes","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.3390/membranes14120251","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Fouling and Chemical Cleaning Strategies for Submerged Ultrafiltration Membrane: Synchronized Bench-Scale, Full-Scale, and Engineering Tests.
This study investigated membrane fouling issues associated with the operation of a submerged ultrafiltration membrane in a drinking water treatment plant (DWTP) and optimized the associated chemical cleaning strategies. By analyzing the surface components of the membrane foulant and the compositions of the membrane cleaning solution, the primary causes of membrane fouling were identified. Membrane fouling control strategies suitable for the DWTP were evaluated through chemical cleaning tests conducted for bench-scale, full-scale, and engineering cases. The results show that the membrane foulants were primarily composed of a mixture of inorganics and organics; the inorganics were mainly composed of Al and Si, while the organics were primarily humic acid (HA). Sodium citrate proved to be the most effective cleaning agent for inorganic fouling, which was mainly composed of Al, whereas sodium hypochlorite (NaClO) combined with sodium hydroxide (NaOH) showed the best removal efficiency for organic fouling, which predominantly consisted of HA and Si. However, sodium hypochlorite (NaClO) combined with sodium hydroxide (NaOH) showed the best removal efficiency for organic fouling and Si; organic fouling predominantly consisted of HA. Based on the bench-scale test results, flux recovery was verified in the full-scale system. Under a constant pressure of 30 kPa, the combined acid-alkali cleaning achieved the best flux recovery, restoring the flux from 22.8 L/(m2·h) to 66.75 L/(m2·h). In the engineering tests, combined acid-alkali cleaning yielded results consistent with those of the full-scale tests. In the practical engineering cleaning process, adopting a cleaning strategy of alkaline (NaClO + NaOH) cleaning followed by acidic (sodium citrate) cleaning can effectively solve the membrane fouling problem.
MembranesChemical Engineering-Filtration and Separation
CiteScore
6.10
自引率
16.70%
发文量
1071
审稿时长
11 weeks
期刊介绍:
Membranes (ISSN 2077-0375) is an international, peer-reviewed open access journal of separation science and technology. It publishes reviews, research articles, communications and technical notes. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. There is no restriction on the length of the papers. Full experimental and/or methodical details must be provided.