双π桥对双（三芳胺）基有机混价体系的影响：以Diaza[1.1]（4,4”）邻苯二甲酸基阳离子为例

IF 3.9 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemistry - A European Journal Pub Date : 2025-01-27 Epub Date: 2025-01-09 DOI:10.1002/chem.202403945

Koshi Yoshida, Fumiya Takasaki, Masashi Uebe, Shu Seki, Akihiro Ito

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引用次数: 0

摘要

制备了一个由两个邻苯二烯基团桥接的双（三芳胺）（BTA）自由基阳离子，并对其进行了表征，探讨了双π桥对2位有机混价（MV）化合物分子内电荷/自旋转移过程的影响。光学和热辅助价间电荷转移（IVCT）过程的光谱分析表明，双π桥接增强了两个氮氧化还原活性中心之间的电荷离域，而与单π桥接对照化合物相比，电子耦合没有增强。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Impact of Double-π-Bridge on Bis(Triarylamine)-Based Organic Mixed-Valence System: A Case Study of Diaza[1.1](4,4")ortho-Terphenylophane Radical Cation.

A bis(triarylamine) (BTA) radical cation, bridged by two o-terphenylene moieties, was prepared and characterized to explore the impact of the double-π-bridge on the intramolecular charge/spin transfer process in the 2-site organic mixed-valence (MV) compound. Spectroscopic analyses on optically and thermally assisted intervalence charge-transfer (IVCT) processes revealed that the doubly π-bridging enhanced the charge delocalization between two nitrogen redox-active centers, whereas the electronic coupling was not so strengthened, in comparison with the singly π-bridging reference compound.

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来源期刊

Chemistry - A European Journal 化学-化学综合

CiteScore

7.90

自引率

4.70%

发文量

1808

审稿时长

1.8 months

期刊介绍： Chemistry—A European Journal is a truly international journal with top quality contributions (2018 ISI Impact Factor: 5.16). It publishes a wide range of outstanding Reviews, Minireviews, Concepts, Full Papers, and Communications from all areas of chemistry and related fields. Based in Europe Chemistry—A European Journal provides an excellent platform for increasing the visibility of European chemistry as well as for featuring the best research from authors from around the world. All manuscripts are peer-reviewed, and electronic processing ensures accurate reproduction of text and data, plus short publication times. The Concepts section provides nonspecialist readers with a useful conceptual guide to unfamiliar areas and experts with new angles on familiar problems. Chemistry—A European Journal is published on behalf of ChemPubSoc Europe, a group of 16 national chemical societies from within Europe, and supported by the Asian Chemical Editorial Societies. The ChemPubSoc Europe family comprises: Angewandte Chemie, Chemistry—A European Journal, European Journal of Organic Chemistry, European Journal of Inorganic Chemistry, ChemPhysChem, ChemBioChem, ChemMedChem, ChemCatChem, ChemSusChem, ChemPlusChem, ChemElectroChem, and ChemistryOpen.