新型竹基磁性生物炭复合材料高效去除诺氟沙星的性能及机理研究

IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES
Cheng Li, Xiang Zhang, Chen Zhou, Fan Yang, Jingyi Liang, Haiping Gu, Jie Wang, Fei Wang, Wanxi Peng, Jianhui Guo, Hanyin Li
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引用次数: 0

摘要

喹诺酮类抗生素已成为水生生态系统中突出的有机污染物,严重威胁着环境和人类健康。以环保的方式有效去除这些污染物仍然是一个挑战。本研究采用koh活化磁化水热法制备了一种简单环保的竹基磁性生物炭,用于去除水中的抗生素诺氟沙星(NOR)。表征结果表明,KOH活化显著提高了竹生物炭的比表面积,KMDBC达到1253.66 m2·g−1。KMDBC对NOR的吸附过程符合拟二级动力学模型和Langmuir等温模型,最大吸附量为458.43 mg·L−1。根据热力学结果,吸附过程是放热的,自发的,并且涉及化学吸附,可能通过π-π相互作用,氢键和静电排斥。该研究表明,KMDBC是一种有效的、可回收的NOR去除材料,为利用森林资源进行环境修复提供了有价值的见解。图形抽象
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Performance and mechanism of a novel bamboo-based magnetic biochar composite for efficient removal of norfloxacin

Performance and mechanism of a novel bamboo-based magnetic biochar composite for efficient removal of norfloxacin

Quinolone antibiotics have become prominent organic contaminants in aquatic ecosystems, significantly threatening the environment and human health. Efficient removal of these pollutants in an eco-friendly manner still remains a challenge. In this study, a simple and environmentally friendly bamboo-based magnetic biochar was prepared by KOH-activated magnetized hydrothermal method to remove the antibiotics norfloxacin (NOR) from water. The characterization results demonstrated that the KOH activation significantly increased the specific surface area of bamboo biochar, with KMDBC reaching 1253.66 m2·g−1. The adsorption process of NOR by KMDBC followed the Pseudo-second order kinetic model and Langmuir isothermal model, with a maximum adsorption capacity of 458.43 mg·L−1. Based on the thermodynamic results, the adsorption process was exothermic, spontaneous, and involved chemisorption, likely through π-π interactions, hydrogen bonding, and electrostatic repulsion. This study demonstrates that KMDBC is an effective and recyclable material for NOR removal, offering valuable insights into utilizing forest resources for environmental remediation.

Graphical abstract

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来源期刊
CiteScore
26.00
自引率
21.40%
发文量
185
期刊介绍: Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field. The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest. Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials. Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.
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