IF 6 3区 工程技术 Q2 ENERGY & FUELS
Solar RRL Pub Date : 2024-11-16 DOI:10.1002/solr.202400571
Andreas Fell, Martin Bivour, Christoph Messmer, Martin Hermle
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引用次数: 0

摘要

薄膜太阳能电池(包括过氧化物硅串联电池)面临的一个挑战是薄膜层的无缺陷沉积。这些缺陷会导致较高的局部寄生电流损耗,即局部分流点。根据缺陷的性质,其几何分布可以是微观的,例如由纹理形态引起,也可以是宏观的,例如由加工过程中的颗粒引起。有人提出了所谓的分流淬火方法来减少相关的效率损失,而不是避免缺陷本身。这项工作研究了最近提出的以下方法:1)故意使电流失配;2)设计子单元之间中间层的电阻特性,从电气上隔离分流。本文介绍了一项全面的三维器件仿真研究,以定量分析这些方法的(不)有效性。研究发现,在电流匹配点的整体优化过程中,通过刻意的电流失配进行分流淬火只能起到微不足道的作用。一般来说,对中间层的电阻特性进行设计必须被视为无效。它只适用于电池单元间变化很小的强分流和宏观分布的特殊情况,而且必须满足电池单元设计的一些进一步要求。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Is Shunt Quenching Relevant to Minimize Shunt Losses in Perovskite–Silicon Tandem Solar Cells?

Is Shunt Quenching Relevant to Minimize Shunt Losses in Perovskite–Silicon Tandem Solar Cells?

One challenge in thin-film based solar cells, including perovskite-silicon tandem cells, is the defect-free deposition of the thin-film layers. Such defects can result in high local parasitic current losses, that is, local shunt spots. Depending on the nature of the defects, their geometrical distribution can either be microscopic, for example, induced by texture morphology, or macroscopic, for example, induced by particles during processing. Instead of avoiding the defects themselves, so-called shunt-quenching methods have been proposed to mitigate the associated efficiency loss. This work investigates the following recently suggested methods: 1) a deliberate current mismatch; and 2) engineering the resistive properties of the intermediate layers between the subcells to electrically isolate the shunt. A comprehensive 3D device simulation study is presented to quantitatively analyze the (in)effectiveness of these methods. It is found that shunt-quenching by a deliberate current mismatch can only play a minor role in the overall optimization of the current match point. Engineering the resistive properties of the intermediate layers must be generally considered ineffective. It only works for the rather specific case of strong and macroscopically distributed shunts with little cell-to-cell variation and only if some further requirements of the cell design are met.

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来源期刊
Solar RRL
Solar RRL Physics and Astronomy-Atomic and Molecular Physics, and Optics
CiteScore
12.10
自引率
6.30%
发文量
460
期刊介绍: Solar RRL, formerly known as Rapid Research Letters, has evolved to embrace a broader and more encompassing format. We publish Research Articles and Reviews covering all facets of solar energy conversion. This includes, but is not limited to, photovoltaics and solar cells (both established and emerging systems), as well as the development, characterization, and optimization of materials and devices. Additionally, we cover topics such as photovoltaic modules and systems, their installation and deployment, photocatalysis, solar fuels, photothermal and photoelectrochemical solar energy conversion, energy distribution, grid issues, and other relevant aspects. Join us in exploring the latest advancements in solar energy conversion research.
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