Aijuan Wang, Xiaping Chen, Hanmin Tang, Fei Huang, Dr. Dongmei Yao
{"title":"具有更强吸附性和光催化活性的 CuO/COF 光催化剂去除甲基绿","authors":"Aijuan Wang, Xiaping Chen, Hanmin Tang, Fei Huang, Dr. Dongmei Yao","doi":"10.1002/slct.202404454","DOIUrl":null,"url":null,"abstract":"<p>In this paper, copper oxide/covalent organic framework (CuO/COF) composites were prepared and investigated the photocatalytic performances for the removal of dyes. The characterization results of FTIR, XRD, and XPS, all proved that the CuO/COF composite were successfully prepared. The mapping of CuO/COF showed that the Cu element was uniformly distributed in the COF. After CuO was composited with COF, the energy band gap <i>E</i><sub>g</sub> decreased from 1.14 eV to 0.81 eV. The highest photocatalytic degradation rate of the CuO/COF composite was 94.00%. At the same time, the photocatalytic wavelength could be shifted from 254 nm to 356 nm. The enhancement of the photocatalytic activity of the CuO/COF composite was attributed to the increase in carrier transfer rate and the increase in the active sites. These results show that the CuO/COF photocatalyst has a strong potential for removing organic dyes under light of 254–356 nm, which also provides a certain reference value for the development of photocatalytic materials.</p>","PeriodicalId":146,"journal":{"name":"ChemistrySelect","volume":"9 47","pages":""},"PeriodicalIF":1.9000,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Removal of Methyl Green by CuO/COF Photocatalysts with Enhanced Adsorption and Photocatalytic Activity\",\"authors\":\"Aijuan Wang, Xiaping Chen, Hanmin Tang, Fei Huang, Dr. Dongmei Yao\",\"doi\":\"10.1002/slct.202404454\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In this paper, copper oxide/covalent organic framework (CuO/COF) composites were prepared and investigated the photocatalytic performances for the removal of dyes. The characterization results of FTIR, XRD, and XPS, all proved that the CuO/COF composite were successfully prepared. The mapping of CuO/COF showed that the Cu element was uniformly distributed in the COF. After CuO was composited with COF, the energy band gap <i>E</i><sub>g</sub> decreased from 1.14 eV to 0.81 eV. The highest photocatalytic degradation rate of the CuO/COF composite was 94.00%. At the same time, the photocatalytic wavelength could be shifted from 254 nm to 356 nm. The enhancement of the photocatalytic activity of the CuO/COF composite was attributed to the increase in carrier transfer rate and the increase in the active sites. These results show that the CuO/COF photocatalyst has a strong potential for removing organic dyes under light of 254–356 nm, which also provides a certain reference value for the development of photocatalytic materials.</p>\",\"PeriodicalId\":146,\"journal\":{\"name\":\"ChemistrySelect\",\"volume\":\"9 47\",\"pages\":\"\"},\"PeriodicalIF\":1.9000,\"publicationDate\":\"2024-12-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemistrySelect\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/slct.202404454\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemistrySelect","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/slct.202404454","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Removal of Methyl Green by CuO/COF Photocatalysts with Enhanced Adsorption and Photocatalytic Activity
In this paper, copper oxide/covalent organic framework (CuO/COF) composites were prepared and investigated the photocatalytic performances for the removal of dyes. The characterization results of FTIR, XRD, and XPS, all proved that the CuO/COF composite were successfully prepared. The mapping of CuO/COF showed that the Cu element was uniformly distributed in the COF. After CuO was composited with COF, the energy band gap Eg decreased from 1.14 eV to 0.81 eV. The highest photocatalytic degradation rate of the CuO/COF composite was 94.00%. At the same time, the photocatalytic wavelength could be shifted from 254 nm to 356 nm. The enhancement of the photocatalytic activity of the CuO/COF composite was attributed to the increase in carrier transfer rate and the increase in the active sites. These results show that the CuO/COF photocatalyst has a strong potential for removing organic dyes under light of 254–356 nm, which also provides a certain reference value for the development of photocatalytic materials.
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ChemistrySelect is the latest journal from ChemPubSoc Europe and Wiley-VCH. It offers researchers a quality society-owned journal in which to publish their work in all areas of chemistry. Manuscripts are evaluated by active researchers to ensure they add meaningfully to the scientific literature, and those accepted are processed quickly to ensure rapid online publication.
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