Thermodynamic and Economic Analysis of the Green Ammonia Synthesis System Driven by Synergistic Hydrogen Production Using Alkaline Water Electrolyzers and Proton Exchange Membrane Electrolyzers

Green ammonia and hydrogen from renewable energy sources have emerged as crucial players during the transition of the chemical industry from a fossil energy-dominated economy to one that is environmentally friendly. This work proposes a green ammonia synthesis system driven by synergistic hydrogen generation using alkaline water electrolyzers (AWE) and proton exchange membrane electrolyzers (PEMEC). The effects of hydrogen-production ratios of PEMEC and AWE on the thermodynamic and economic performance of the system are compared and analyzed via multi-objective optimization. The findings showed that an increase in the amount of hydrogen produced by PEMEC improves the system's energy efficiency, but the payback period is delayed because of the PEMEC high initial investment cost. The techno-economic performance of the system at a 1:1 ratio of PEMEC to AWE hydrogen production are investigated considering the system level heat integration based on the pinch point analysis method to maximize the heat recovery. The results show that increasing the operational temperature, the pressure of the electrolyzer, and the ammonia synthesis pressure will enhance the system's thermal performance. Economic analysis shows that reducing electricity prices and electrolyzer investment costs will be the key to achieving the economic feasibility of the green ammonia system.