基于 M6-、M9- 和 M12-簇的金属-卤化物-金属化合物

IF 2 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

European Journal of Inorganic Chemistry Pub Date : 2024-09-30 DOI:10.1002/ejic.202400434

Markus Ströbele, David Enseling, Thomas Jüstel, Mojtaba Abbasi, Scott Kroeker, Hans-Jürgen Meyer

引用次数: 0

摘要

M9-和m12 -金属团簇在（Pb9Br19）2(Pb1.5Br2)2(melem)3(6)中表现为面共享双团簇，在（Pb12Br25）4(Pb1.67Br2)3(melem)4(7)中表现为三团簇。所有化合物都通过单晶和粉末x射线衍射进行了表征，并通过红外（IR）光谱和207Pb和79/81Br核磁共振(5)进一步验证。化合物(6)的光致发光研究显示在430 nm处发射，而(5)的发射完全淬灭。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Metal-Halide–Melem Compounds Based on M6-, M9- and M12-Clusters

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Metal-Halide–Melem Compounds Based on M6-, M9- and M12-Clusters

M₉- and M₁₂-metal clusters appear as face-sharing double-clusters in (Pb₉Br₁₉)₂(Pb_1.5Br₂)₂(melem)₃ (6) and as triple-clusters in (Pb₁₂Br₂₅)₄(Pb_1.67Br₂)₃(melem)₄ (7). All compounds are characterized by single-crystal and powder X-ray diffraction, and further validated by infrared (IR) spectroscopy and ²⁰⁷Pb and ^79/81Br NMR studies on (5). Photoluminescence studies on compound (6) reveal emission at 430 nm while the emission of (5) is completely quenched.

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来源期刊

European Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

4.30

自引率

4.30%

发文量

419

审稿时长

1.3 months

期刊介绍： The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.