Hayato Goto, Kosei Ito, Shivaji B. Sadale, Kei Noda
{"title":"Gas Phase CO2 Photoreduction Behaviors over Composites of Galvanostatically Pulse-Deposited Cu2O Nanoparticles and Anodized TiO2 Nanotube Arrays","authors":"Hayato Goto, Kosei Ito, Shivaji B. Sadale, Kei Noda","doi":"10.1002/adem.202302249","DOIUrl":null,"url":null,"abstract":"<p>Electrochemically synthesized composites of vertically aligned titanium dioxide (TiO<sub>2</sub>) nanotube arrays (TNAs) and cuprous oxide (Cu<sub>2</sub>O) nanoparticles (CNPs) are used for studying gas phase CO<sub>2</sub> photoreduction behaviors. Anodized TNA surfaces with an average aperture size of 60 nm are decorated with CNPs using galvanostatic pulse electrodeposition. The nucleation and growth of CNPs are investigated with the help of cyclic voltammetry and potential-time transients. The number of CNPs and their distribution on TNA surfaces are widely altered by adjusting the ON/OFF time, the number of applied current pulse, and the bath temperature. After characterizing structural and physical properties of the prepared CNPs/TNAs samples, in situ observation of CO<sub>2</sub> photoreduction in gas phase over CNPs/TNAs is carried out in a high vacuum. The enhancement in CO<sub>2</sub> photoreduction over CNPs/TNAs samples is observed for the optimized size and the number of CNPs on TNAs. The reaction route of the same is ascertained from the reaction products. The experimental results indicate that the size of CNPs should be comparable to the average pore size of TNAs for promoting CO<sub>2</sub> photoreduction, and the relationship between CO<sub>2</sub> photoreduction and the structural properties of CNPs is further discussed.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"26 23","pages":""},"PeriodicalIF":3.4000,"publicationDate":"2024-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adem.202302249","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Engineering Materials","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/adem.202302249","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Gas Phase CO2 Photoreduction Behaviors over Composites of Galvanostatically Pulse-Deposited Cu2O Nanoparticles and Anodized TiO2 Nanotube Arrays
Electrochemically synthesized composites of vertically aligned titanium dioxide (TiO2) nanotube arrays (TNAs) and cuprous oxide (Cu2O) nanoparticles (CNPs) are used for studying gas phase CO2 photoreduction behaviors. Anodized TNA surfaces with an average aperture size of 60 nm are decorated with CNPs using galvanostatic pulse electrodeposition. The nucleation and growth of CNPs are investigated with the help of cyclic voltammetry and potential-time transients. The number of CNPs and their distribution on TNA surfaces are widely altered by adjusting the ON/OFF time, the number of applied current pulse, and the bath temperature. After characterizing structural and physical properties of the prepared CNPs/TNAs samples, in situ observation of CO2 photoreduction in gas phase over CNPs/TNAs is carried out in a high vacuum. The enhancement in CO2 photoreduction over CNPs/TNAs samples is observed for the optimized size and the number of CNPs on TNAs. The reaction route of the same is ascertained from the reaction products. The experimental results indicate that the size of CNPs should be comparable to the average pore size of TNAs for promoting CO2 photoreduction, and the relationship between CO2 photoreduction and the structural properties of CNPs is further discussed.
期刊介绍:
Advanced Engineering Materials is the membership journal of three leading European Materials Societies
- German Materials Society/DGM,
- French Materials Society/SF2M,
- Swiss Materials Federation/SVMT.