Cadianne Chambers, Savannah Grimes, Russell C Smith, Ayden Weil, M Toufiq Reza
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摘要

本研究重点介绍了利用龙柏提取的生物炭去除水中有害藻华毒素--沙西毒素(STX)的方法。生物炭样品是在不同的热解温度(400、600 和 800 ℃)下经过 60 分钟制备而成的。随着热解温度的升高,观察到表面孔隙率增加(SBET = 7.26 ± 0.2 m2/g 至 408.15 ± 6.19 m2/g),同时观察到含氧官能团减少(1517.80 ± 14.98 μmol/g 至 823.01 ± 7.72 μmol/g)。这项研究旨在发现生物炭用量、接触时间、初始浓度和初始 pH 值等吸附参数对沙西毒素吸附的影响。研究结果令人印象深刻,当生物炭的用量为 0.01 克/升、接触时间为 30 分钟时,毒素的去除率大于 90%;随着水中 STX 初始浓度和初始 pH 值的增加,毒素的去除率也在增加。P400 的吸附容量最大,为 314.37 μg/g。这表明,表面官能团对 STX 的吸附具有更高的亲和力,这可能是由于氢键、静电作用、离子交换和 π-π 相互作用。所应用的动力学模型显示了物理吸附和化学吸附的相互作用,其中艾洛维奇模型的拟合效果最好。作为补充,吸附等温线分析证实了 Freundlich 模型的多层吸附行为。因此,这些研究结果支持将生物炭材料用于修复 STX 水体。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Investigation of adsorption parameters of saxitoxin onto loblolly pine-derived biochar synthesized at various pyrolysis temperature.

This study highlights the use of loblolly pine derived biochar for the removal of harmful algal bloom toxin, Saxitoxin (STX), from water. Biochar samples were prepared at varying pyrolysis temperatures (400, 600 and 800 °C) for 60 min. As pyrolysis temperature increases, enhancement in surface porosity was observed (SBET = 7.26 ± 0.2 m2/g to 408.15 ± 6.19 m2/g) while a decline in oxygen-containing functional groups was observed (1517.80 ± 14.98 μmol/g to 823.01 ± 7.72 μmol/g). This study aimed to discover the effects of adsorption parameters such as biochar dosage amount, contact time, initial concentration and initial pH on Saxitoxin adsorption. These studies revealed impressive results with >90 % toxin removal with dosage rate of 0.01 g/L, contact time of 30 min, and increasing percent removal with increasing initial STX concentration and initial pH in water. Maximum uptake was calculated for P400 with adsorption capacity of 314.37 μg/g. This showed that surface functionality showed higher affinity for STX uptake, which may be possible due to hydrogen bonding, electrostatic interactions, ion-exchange, and π-π interactions. Applied kinetic models indicated both physisorption and chemisorption interactions with best fit supporting the Elovich models. Complementary, adsorption isotherm analysis confirmed the multilayer adsorption behavior of the Freundlich model. Therefore, these findings support the viable use of biochar material for the remediation of STX waters.

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