inenr cktitelbild:界面触发稀土粒子内异质结构纳米合金的自旋磁效应促进析氢[j]。化学52/2024)

Hengjun Liu, Yong Jiang, Qingqing Li, Dr. Guangtong Hai, Dr. Chao Gu, Prof. Dr. Yaping Du
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引用次数: 0

摘要

稀土元素由于其独特的4f电子组态和强轨道耦合而具有自旋磁调制的吸引力。顾超,杜亚平等在其研究论文(e202412591)中。定义了一种固相合成方案,用于在整个Rh框架内创建具有不同Gd和Co界面的RE-3d过渡金属-贵金属集成颗粒内异质结构纳米合金。它们表现出界面触发的反铁磁相互作用,可以诱导电子重分布并调节自旋极化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Innenrücktitelbild: Interface-Triggered Spin-Magnetic Effect in Rare Earth Intraparticle Heterostructured Nanoalloys for Boosting Hydrogen Evolution (Angew. Chem. 52/2024)

Innenrücktitelbild: Interface-Triggered Spin-Magnetic Effect in Rare Earth Intraparticle Heterostructured Nanoalloys for Boosting Hydrogen Evolution (Angew. Chem. 52/2024)

Rare earth (RE) elements are attractive for spin-magnetic modulation due to their unique 4f electron configuration and strong orbital couplings. In their Research Article (e202412591), Chao Gu, Yaping Du et al. define a solid-phase synthetic protocol for creating RE-3d transition metal–noble metal integrated intraparticle heterostructured nanoalloys with distinct Gd and Co interface within the entire Rh framework. They exhibit interface-triggered antiferromagnetic interaction, which can induce electron redistribution and regulate spin polarization.

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来源期刊
Angewandte Chemie
Angewandte Chemie 化学科学, 有机化学, 有机合成
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