{"title":"Ce-MOF 中有机配体的配位效应使 Fe 原子分散在 CeO2 中，用于检测商业样品中的 TAC。","authors":"Lulu Cui, Houshen Li, Weijie Shi, Yingying Jing, Shuhong Sun, Shiyun Ai, Zeyi Guo","doi":"10.1016/j.talanta.2024.127405","DOIUrl":null,"url":null,"abstract":"<p><p>Reducing the size of active species is a powerful means to improve the utilization rate of active metals and enhance the properties of bimetallic nanozymes. In this work, Fe was introduced into Ce-MOF through the coordination of Fe<sup>3+</sup> and organic ligands, and the coordination effect resulted in atomically dispersed Fe in the derived Fe/CeO<sub>2</sub> nanozyme. Due to the atomically dispersed Fe embedded in the lattice of CeO<sub>2</sub>, a large number of defect sites were generated, endowing the nanozyme with excellent peroxidase (POD)-like activity. The constructed total antioxidant capacity (TAC) sensor based on the POD-like activity of Fe<sub>1.01</sub>/CeO<sub>2</sub> nanozyme displayed a very wide linear concentration range for AA, Cys, Glu and Trolox. More importantly, this TAC sensor can be applied to the TAC detection in vitamin C tablets and beverages. This work provides theoretical guidance for the synthesis of high-performance bimetallic nanozymes for TAC detection.</p>","PeriodicalId":435,"journal":{"name":"Talanta","volume":"285 ","pages":"127405"},"PeriodicalIF":5.6000,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The coordination effect of organic ligands in Ce-MOF brings about atomically dispersed Fe in CeO<sub>2</sub> for TAC detection in commercial samples.\",\"authors\":\"Lulu Cui, Houshen Li, Weijie Shi, Yingying Jing, Shuhong Sun, Shiyun Ai, Zeyi Guo\",\"doi\":\"10.1016/j.talanta.2024.127405\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Reducing the size of active species is a powerful means to improve the utilization rate of active metals and enhance the properties of bimetallic nanozymes. In this work, Fe was introduced into Ce-MOF through the coordination of Fe<sup>3+</sup> and organic ligands, and the coordination effect resulted in atomically dispersed Fe in the derived Fe/CeO<sub>2</sub> nanozyme. Due to the atomically dispersed Fe embedded in the lattice of CeO<sub>2</sub>, a large number of defect sites were generated, endowing the nanozyme with excellent peroxidase (POD)-like activity. The constructed total antioxidant capacity (TAC) sensor based on the POD-like activity of Fe<sub>1.01</sub>/CeO<sub>2</sub> nanozyme displayed a very wide linear concentration range for AA, Cys, Glu and Trolox. More importantly, this TAC sensor can be applied to the TAC detection in vitamin C tablets and beverages. This work provides theoretical guidance for the synthesis of high-performance bimetallic nanozymes for TAC detection.</p>\",\"PeriodicalId\":435,\"journal\":{\"name\":\"Talanta\",\"volume\":\"285 \",\"pages\":\"127405\"},\"PeriodicalIF\":5.6000,\"publicationDate\":\"2024-12-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Talanta\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1016/j.talanta.2024.127405\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Talanta","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1016/j.talanta.2024.127405","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
The coordination effect of organic ligands in Ce-MOF brings about atomically dispersed Fe in CeO2 for TAC detection in commercial samples.
Reducing the size of active species is a powerful means to improve the utilization rate of active metals and enhance the properties of bimetallic nanozymes. In this work, Fe was introduced into Ce-MOF through the coordination of Fe3+ and organic ligands, and the coordination effect resulted in atomically dispersed Fe in the derived Fe/CeO2 nanozyme. Due to the atomically dispersed Fe embedded in the lattice of CeO2, a large number of defect sites were generated, endowing the nanozyme with excellent peroxidase (POD)-like activity. The constructed total antioxidant capacity (TAC) sensor based on the POD-like activity of Fe1.01/CeO2 nanozyme displayed a very wide linear concentration range for AA, Cys, Glu and Trolox. More importantly, this TAC sensor can be applied to the TAC detection in vitamin C tablets and beverages. This work provides theoretical guidance for the synthesis of high-performance bimetallic nanozymes for TAC detection.
期刊介绍：
Talanta provides a forum for the publication of original research papers, short communications, and critical reviews in all branches of pure and applied analytical chemistry. Papers are evaluated based on established guidelines, including the fundamental nature of the study, scientific novelty, substantial improvement or advantage over existing technology or methods, and demonstrated analytical applicability. Original research papers on fundamental studies, and on novel sensor and instrumentation developments, are encouraged. Novel or improved applications in areas such as clinical and biological chemistry, environmental analysis, geochemistry, materials science and engineering, and analytical platforms for omics development are welcome.
Analytical performance of methods should be determined, including interference and matrix effects, and methods should be validated by comparison with a standard method, or analysis of a certified reference material. Simple spiking recoveries may not be sufficient. The developed method should especially comprise information on selectivity, sensitivity, detection limits, accuracy, and reliability. However, applying official validation or robustness studies to a routine method or technique does not necessarily constitute novelty. Proper statistical treatment of the data should be provided. Relevant literature should be cited, including related publications by the authors, and authors should discuss how their proposed methodology compares with previously reported methods.
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