以单质硒、烯烃和腈为原料合成新型1,3-硒代唑啉的一般方法

IF 0.9 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Russian Journal of General Chemistry Pub Date : 2024-12-17 DOI:10.1134/S1070363224110112

E. O. Kurkutov, A. B. Ivanova, S. Yu. Gubal, S. V. Zinchenko, B. A. Shainyan

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引用次数: 0

摘要

将碘介导单质硒、烯烃和乙腈反应合成1,3-硒代唑啉的策略扩展到二烯和其他腈，得到了新的硒代唑啉。二烯的两个双键中只有一个参与了硒化唑啉环的形成。苯并或丁腈只有在使用乙酸乙酯作为共溶剂时才能进入反应。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

General Method for the Synthesis of New 1,3-Selenazolines from Elemental Selenium, Alkenes, and Nitriles

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General Method for the Synthesis of New 1,3-Selenazolines from Elemental Selenium, Alkenes, and Nitriles

The strategy of the synthesis of 1,3-selenazolines by the iodine-mediated reaction of elemental selenium, alkenes and acetonitrile is extended to dienes and other nitriles, and new selenazolines are obtained. Only one of the two double bonds in dienes is involved in the selenazoline ring formation. Benzo- or butyronitriles enter the reaction only when using ethyl acetate as a co-solvent.

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来源期刊

Russian Journal of General Chemistry 化学-化学综合

CiteScore

1.40

自引率

22.20%

发文量

252

审稿时长

2-4 weeks

期刊介绍： Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.