主电弧电流对等离子传输弧焊制备的 NiCrBSi-WC 合金涂层微观结构和抗气蚀性的影响

IF 3.2 3区 材料科学 Q2 MATERIALS SCIENCE, COATINGS & FILMS
G. X. Zhou, T. Zhao, M. S. Wang, C. L. Wu, S. Zhang, C. H. Zhang, H. T. Chen, J. Chen
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引用次数: 0

摘要

研究了主电弧电流对等离子转移弧焊NiCrBSi-WC合金镀层组织、电化学性能和抗空泡侵蚀性能的影响。结果表明,该涂层由γ-Ni、WC、W2C、Cr7C3、CrB和FeNi3相组成。随着主弧电流的减小,组织逐渐细化,晶粒尺寸减小,施密特系数减小,分别为12.62±2.6 μm和0.42 μm。同时,涂层具有较强的(111)取向γ-Ni织构。涂层组织的细化和表面钝化膜的存在减缓了硼酸溶液中的电化学腐蚀,有效地提高了涂层的耐蚀性。显微硬度的提高主要是由于WC和Cr7C3的第二相强化机制,最大值可达663.5±6.2 HV。采用气蚀协同法研究了涂层钝化膜的损伤与修复过程。随着主弧电流的增大,镀层的平均腐蚀深度速率(MDER)可降至1.02±0.03 μm/h,这是由于钝化膜的独立修复能力提高所致,显微硬度测试结果与MDER呈负相关。根据上述分析结果,提出了NiCrBSi-WC合金镀层空化腐蚀的协同机理。本研究采用等离子转移弧焊技术制备的NiCrBSi-WC合金涂层在核工业中具有很大的应用前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of Main Arc Current on Microstructure and Cavitation Resistance of NiCrBSi-WC Alloy Coating Prepared by Plasma Transfer Arc Welding

The effect of main arc current on the microstructure, electrochemical properties, and cavitation erosion resistance of NiCrBSi-WC alloy coating by plasma transfer arc welding was studied. The results show that the coating is composed of γ-Ni, WC, W2C, Cr7C3, CrB, and FeNi3 phases. With the decrease in main arc current, the microstructure is gradually refined, and the grain size and Schmidt factor are reduced, which are 12.62 ± 2.6 μm and 0.42, respectively. At the same time, the coating has a strong γ-Ni texture in (111) orientation. The refinement of the coating microstructure and the existence of surface passivation film slow down the electrochemical corrosion in boric acid solution and effectively improve the corrosion resistance of the coating. The increase in microhardness is due to the second phase strengthening mechanism of WC and Cr7C3, and the maximum value can reach 663.5 ± 6.2 HV. The damage and repair process of the passive film of the coating was studied by the synergistic method of cavitation erosion. With the increase in the main arc current, the average corrosion depth rate (MDER) of the coating can be reduced to 1.02 ± 0.03 μm/h, which is due to the improvement of the independent repair ability of the passive film, and the microhardness test results are inversely related to MDER. According to the above analysis results, the synergistic mechanism of cavitation corrosion of NiCrBSi-WC alloy coating is put forward. NiCrBSi-WC alloy coating prepared by plasma transfer arc welding technology in this study has great application prospects in the nuclear industry.

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来源期刊
Journal of Thermal Spray Technology
Journal of Thermal Spray Technology 工程技术-材料科学:膜
CiteScore
5.20
自引率
25.80%
发文量
198
审稿时长
2.6 months
期刊介绍: From the scientific to the practical, stay on top of advances in this fast-growing coating technology with ASM International''s Journal of Thermal Spray Technology. Critically reviewed scientific papers and engineering articles combine the best of new research with the latest applications and problem solving. A service of the ASM Thermal Spray Society (TSS), the Journal of Thermal Spray Technology covers all fundamental and practical aspects of thermal spray science, including processes, feedstock manufacture, and testing and characterization. The journal contains worldwide coverage of the latest research, products, equipment and process developments, and includes technical note case studies from real-time applications and in-depth topical reviews.
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