N. I. Cherkashina, V. I. Pavlenko, A. Y. Ruchii, S. N. Domarev, E. V. Forova
{"title":"真空紫外线辐射对基于填充了二氧化硅的聚酰亚胺轨道膜的复合材料的傅立叶变换红外吸收光谱变化以及电气和疏水性能的影响","authors":"N. I. Cherkashina, V. I. Pavlenko, A. Y. Ruchii, S. N. Domarev, E. V. Forova","doi":"10.1134/S1027451024700782","DOIUrl":null,"url":null,"abstract":"<p>Vacuum ultraviolet radiation is a part of ultraviolet radiation with a very short wavelength and is a component of cosmic radiation. Composite materials based on polyimide have great potential for protection against cosmic radiation. The paper presents the results of studies on the effect of vacuum ultraviolet radiation on a polyimide film, a polyimide track membrane, and a composite material based on the polyimide track membrane filled with silica nanofibers. Mass losses, dielectric properties, Fourier-transform infrared spectra, and wettability of the studied samples before and after vacuum ultraviolet irradiation were studied. It was found that the lowest mass losses during vacuum ultraviolet irradiation were observed in the composite material based on the polyimide track membrane filled with SiO<sub>2</sub>; the dielectric constant of the composite film after vacuum ultraviolet irradiation increased by 65.8%. It was established that the effect of vacuum ultraviolet radiation on the films under study was accompanied by destruction of a small number of the following bonds: C=O, C–O, C–C, and C–N. At the same time, vacuum ultraviolet radiation caused the least damage to the developed composite material. Contact angle analysis of the studied samples showed that the surface of the polyimide film, polyimide track membrane, and composite material remained hydrophilic after irradiation. No changes were detected in the structure of the film surface.</p>","PeriodicalId":671,"journal":{"name":"Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques","volume":"18 5","pages":"1033 - 1040"},"PeriodicalIF":0.5000,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of Vacuum Ultraviolet Radiation on Changes in Fourier-Transform Infrared Absorption Spectra and Electrical and Hydrophobic Properties of a Composite Based on Polyimide Track Membranes Filled with Silica\",\"authors\":\"N. I. Cherkashina, V. I. Pavlenko, A. Y. Ruchii, S. N. Domarev, E. V. Forova\",\"doi\":\"10.1134/S1027451024700782\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Vacuum ultraviolet radiation is a part of ultraviolet radiation with a very short wavelength and is a component of cosmic radiation. Composite materials based on polyimide have great potential for protection against cosmic radiation. The paper presents the results of studies on the effect of vacuum ultraviolet radiation on a polyimide film, a polyimide track membrane, and a composite material based on the polyimide track membrane filled with silica nanofibers. Mass losses, dielectric properties, Fourier-transform infrared spectra, and wettability of the studied samples before and after vacuum ultraviolet irradiation were studied. It was found that the lowest mass losses during vacuum ultraviolet irradiation were observed in the composite material based on the polyimide track membrane filled with SiO<sub>2</sub>; the dielectric constant of the composite film after vacuum ultraviolet irradiation increased by 65.8%. It was established that the effect of vacuum ultraviolet radiation on the films under study was accompanied by destruction of a small number of the following bonds: C=O, C–O, C–C, and C–N. At the same time, vacuum ultraviolet radiation caused the least damage to the developed composite material. Contact angle analysis of the studied samples showed that the surface of the polyimide film, polyimide track membrane, and composite material remained hydrophilic after irradiation. No changes were detected in the structure of the film surface.</p>\",\"PeriodicalId\":671,\"journal\":{\"name\":\"Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques\",\"volume\":\"18 5\",\"pages\":\"1033 - 1040\"},\"PeriodicalIF\":0.5000,\"publicationDate\":\"2024-12-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1027451024700782\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, CONDENSED MATTER\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1134/S1027451024700782","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, CONDENSED MATTER","Score":null,"Total":0}
引用次数: 0
摘要
真空紫外线辐射是波长很短的紫外线辐射的一部分，是宇宙辐射的一个组成部分。以聚酰亚胺为基础的复合材料在防止宇宙辐射方面具有很大的潜力。本文介绍了真空紫外辐射对聚酰亚胺薄膜、聚酰亚胺轨道膜和填充二氧化硅纳米纤维的聚酰亚胺轨道膜复合材料的影响。研究了真空紫外辐照前后样品的质量损失、介电性能、傅里叶变换红外光谱和润湿性。结果表明，在真空紫外照射下，以SiO2填充的聚酰亚胺轨道膜为基础的复合材料的质量损失最小；真空紫外辐照后，复合膜的介电常数提高了65.8%。结果表明，真空紫外辐射对薄膜的影响伴随着以下几个键的破坏：C=O, C - O， C - C和C - n。同时，真空紫外辐射对所研制的复合材料的损伤最小。接触角分析表明，辐照后聚酰亚胺薄膜、聚酰亚胺轨道膜和复合材料表面均保持亲水性。膜表面结构未发生变化。
Influence of Vacuum Ultraviolet Radiation on Changes in Fourier-Transform Infrared Absorption Spectra and Electrical and Hydrophobic Properties of a Composite Based on Polyimide Track Membranes Filled with Silica
Vacuum ultraviolet radiation is a part of ultraviolet radiation with a very short wavelength and is a component of cosmic radiation. Composite materials based on polyimide have great potential for protection against cosmic radiation. The paper presents the results of studies on the effect of vacuum ultraviolet radiation on a polyimide film, a polyimide track membrane, and a composite material based on the polyimide track membrane filled with silica nanofibers. Mass losses, dielectric properties, Fourier-transform infrared spectra, and wettability of the studied samples before and after vacuum ultraviolet irradiation were studied. It was found that the lowest mass losses during vacuum ultraviolet irradiation were observed in the composite material based on the polyimide track membrane filled with SiO2; the dielectric constant of the composite film after vacuum ultraviolet irradiation increased by 65.8%. It was established that the effect of vacuum ultraviolet radiation on the films under study was accompanied by destruction of a small number of the following bonds: C=O, C–O, C–C, and C–N. At the same time, vacuum ultraviolet radiation caused the least damage to the developed composite material. Contact angle analysis of the studied samples showed that the surface of the polyimide film, polyimide track membrane, and composite material remained hydrophilic after irradiation. No changes were detected in the structure of the film surface.
期刊介绍：
Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques publishes original articles on the topical problems of solid-state physics, materials science, experimental techniques, condensed media, nanostructures, surfaces of thin films, and phase boundaries: geometric and energetical structures of surfaces, the methods of computer simulations; physical and chemical properties and their changes upon radiation and other treatments; the methods of studies of films and surface layers of crystals (XRD, XPS, synchrotron radiation, neutron and electron diffraction, electron microscopic, scanning tunneling microscopic, atomic force microscopic studies, and other methods that provide data on the surfaces and thin films). Articles related to the methods and technics of structure studies are the focus of the journal. The journal accepts manuscripts of regular articles and reviews in English or Russian language from authors of all countries. All manuscripts are peer-reviewed.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
