氧化石墨烯纳米颗粒对水泥砂浆的影响:机械、微观结构和耐久性能

IF 0.9 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY
P. V. Reshma Raj, S. Judes Sujatha
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引用次数: 0

摘要

在水泥及其应用领域,纳米材料,尤其是碳基材料总是受到研究人员的更多关注。水泥基复合材料中最常见的添加剂是石墨烯和其他碳基衍生物。本研究探讨了氧化石墨烯(GO)对水泥砂浆的影响,GO 的添加比例为水泥重量的 0.01% 至 0.05%,间隔为 0.01%。水灰比(w/c)为 0.5 的 1 : 1.5 水泥砂浆在所有混合器中均保持不变。对流动性和初凝时间等新拌特性进行了检测,结果表明 GO 增强材料会影响初凝时间(约 10-24%),并降低流动性(最多 35%)。力学测试结果表明,当添加量为水泥重量的 0.03% 时,GO 可显著提高抗折强度和抗压强度,提高幅度分别为 30% 和 55%。同时,扫描电镜分析表明,GO 的添加增强了微观结构并减小了孔径。利用吸水率和快速氯化物渗透试验对耐久性能进行的评估表明,添加了 GO 的试样比对照试样具有更好的耐久性,其中 0.05% 添加量的试样具有最高的耐久性。然而,当石墨烯的用量超过最佳用量时,石墨烯会发生团聚,从而导致强度降低并影响微观结构。总之,研究表明,氧化石墨烯(GO)可能是增强水泥复合材料机械性能和耐久性的潜在纳米添加剂之一。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Impact of Graphene Oxide Nanoparticles on Cement Mortar: Mechanical, Microstructure and Durability Properties

Impact of Graphene Oxide Nanoparticles on Cement Mortar: Mechanical, Microstructure and Durability Properties

Nano materials, particularly carbon base always get more attention from the researchers in the domain on cement and its application. The most prevalent additives in cementitious composites are graphene and other carbon-based derivative. This research examines the impact of Graphene Oxide (GO) on cement mortar, with GO added at ratios ranging from 0.01 to 0.05% by weight of the cement, in intervals of 0.01%. The 1 : 1.5 mortar with water cement ratio (w/c) of 0.5 is constant for all the mixers. The fresh property like flowability and initial setting time were examined, the result indicates that the GO-reinforcement affect the initial setting time (about 10–24%) as well as reduces the flowability (up to 35%). The mechanical test result revealed that the GO inclusion substantially improved both flexural and compressive strength for 30 and 55% respectively at the dosage of 0.03% by the weight of cement. Meanwhile the SEM analysis showed that the GO addition enhances the microstructure as well as reduces the pore size. The durability properties as evaluated using water absorption and a rapid chloride penetration test revealed that GO incorporated specimen exhibits better resistance rather than control specimens with the highest resistance achieved on 0.05% dosage samples. However, beyond the optimum amount of GO dosage, agglomeration occurs thus leading to the reduction in strength and affecting the micro structure. In general, the study revealed that graphene oxide (GO) might have one of the potential nano additives to enhance the mechanical and durability of cement composites.

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来源期刊
CiteScore
1.40
自引率
22.20%
发文量
252
审稿时长
2-4 weeks
期刊介绍: Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.
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