{"title":"无机调酸策略对钠离子电池正极材料性能的影响","authors":"Xiangnan Li, Mengdan Zhang, Xinyu Tang, Xiaojian Liu, Yange Yang, Yiwei Xu, Huishuang Zhang, Yanhong Yin* and Shu-Ting Yang*, ","doi":"10.1021/acssuschemeng.4c0832610.1021/acssuschemeng.4c08326","DOIUrl":null,"url":null,"abstract":"<p >The cathode material NaNi<sub>1/3</sub>Fe<sub>1/3</sub>Mn<sub>1/3</sub>O<sub>2</sub> (NFM111) is known as an O3-type layered oxide for sodium ion batteries. It has the advantages of high energy density and easy synthesis. However, the residual alkali leads to capacity decay and air stability decline. And its storage and application are limited. The residual alkali content on the surface of NFM111 is reduced through phosphoric acid treatment. The initial discharge capacity of the modified material is 162 mA h g<sup>–1</sup> at 0.1 C. Meanwhile, the material still has a capacity of 140.7 mA h g<sup>–1</sup> at 0.1 C after exposure to air. This treatment strategy increases the specific discharge capacity of the material at 25 and −20 °C and improves the cycle stability and air stability. It provides an effective and reliable method for the production and application of sodium ion battery cathode materials.</p>","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"12 50","pages":"18296–18304 18296–18304"},"PeriodicalIF":7.3000,"publicationDate":"2024-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Excellent Performance of Sodium Ion Battery Cathode Materials Benefiting from the Inorganic Acid Regulating Strategy\",\"authors\":\"Xiangnan Li, Mengdan Zhang, Xinyu Tang, Xiaojian Liu, Yange Yang, Yiwei Xu, Huishuang Zhang, Yanhong Yin* and Shu-Ting Yang*, \",\"doi\":\"10.1021/acssuschemeng.4c0832610.1021/acssuschemeng.4c08326\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >The cathode material NaNi<sub>1/3</sub>Fe<sub>1/3</sub>Mn<sub>1/3</sub>O<sub>2</sub> (NFM111) is known as an O3-type layered oxide for sodium ion batteries. It has the advantages of high energy density and easy synthesis. However, the residual alkali leads to capacity decay and air stability decline. And its storage and application are limited. The residual alkali content on the surface of NFM111 is reduced through phosphoric acid treatment. The initial discharge capacity of the modified material is 162 mA h g<sup>–1</sup> at 0.1 C. Meanwhile, the material still has a capacity of 140.7 mA h g<sup>–1</sup> at 0.1 C after exposure to air. This treatment strategy increases the specific discharge capacity of the material at 25 and −20 °C and improves the cycle stability and air stability. It provides an effective and reliable method for the production and application of sodium ion battery cathode materials.</p>\",\"PeriodicalId\":25,\"journal\":{\"name\":\"ACS Sustainable Chemistry & Engineering\",\"volume\":\"12 50\",\"pages\":\"18296–18304 18296–18304\"},\"PeriodicalIF\":7.3000,\"publicationDate\":\"2024-11-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Sustainable Chemistry & Engineering\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acssuschemeng.4c08326\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Sustainable Chemistry & Engineering","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acssuschemeng.4c08326","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
负极材料NaNi1/3Fe1/3Mn1/3O2 （NFM111）被称为钠离子电池的o3型层状氧化物。它具有能量密度高、易于合成等优点。然而，残碱导致容量衰减和空气稳定性下降。其存储和应用受到限制。通过磷酸处理，降低了NFM111表面残碱含量。在0.1℃下，改性材料的初始放电容量为162 mA h g-1，在0.1℃下，材料暴露于空气后仍具有140.7 mA h g-1的放电容量。这种处理策略增加了材料在25°C和- 20°C下的比放电容量，提高了循环稳定性和空气稳定性。为钠离子电池正极材料的生产和应用提供了一种有效可靠的方法。
Excellent Performance of Sodium Ion Battery Cathode Materials Benefiting from the Inorganic Acid Regulating Strategy
The cathode material NaNi1/3Fe1/3Mn1/3O2 (NFM111) is known as an O3-type layered oxide for sodium ion batteries. It has the advantages of high energy density and easy synthesis. However, the residual alkali leads to capacity decay and air stability decline. And its storage and application are limited. The residual alkali content on the surface of NFM111 is reduced through phosphoric acid treatment. The initial discharge capacity of the modified material is 162 mA h g–1 at 0.1 C. Meanwhile, the material still has a capacity of 140.7 mA h g–1 at 0.1 C after exposure to air. This treatment strategy increases the specific discharge capacity of the material at 25 and −20 °C and improves the cycle stability and air stability. It provides an effective and reliable method for the production and application of sodium ion battery cathode materials.
期刊介绍：
ACS Sustainable Chemistry & Engineering is a prestigious weekly peer-reviewed scientific journal published by the American Chemical Society. Dedicated to advancing the principles of green chemistry and green engineering, it covers a wide array of research topics including green chemistry, green engineering, biomass, alternative energy, and life cycle assessment.
The journal welcomes submissions in various formats, including Letters, Articles, Features, and Perspectives (Reviews), that address the challenges of sustainability in the chemical enterprise and contribute to the advancement of sustainable practices. Join us in shaping the future of sustainable chemistry and engineering.
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