Direct Monomer Recovery from Ring-Closing Depolymerization of Thermosets

Recovering monomers from the depolymerization of thermosets presents a significant challenge, which becomes even more daunting if one sets the goal of doing it directly, i.e., without complex chemical separation steps. To this end, we have synthesized a new type of polycarbonate thermoset by first copolymerizing alkyl cyclic carbonates (ACCs) with small amounts of allyloxy cyclic carbonates (AoCCs), followed by cross-linking the resulting allyloxy polycarbonate with excess tetrathiol compounds under UV irradiation. These cross-linked polycarbonates demonstrate enhanced thermal and mechanical properties compared to their linear analogues, while maintaining the linear polymers’ capacity for ring-closing depolymerization. The depolymerization process enables the direct recovery of ACC and its dimer, bypassing complex chemical separation steps that are commonly employed in the recycling of conventional chemically recyclable thermosets. The yields range from 74.7% to 91.7% depending on the ratios of AoCC to ACC in the thermosets. Furthermore, the recovered compounds can be repolymerized with AoCCs leading to polycarbonate of the same quality to the initially synthesized one.