界面电荷转移及其对 LaNiO 3 /LaFeO 3 超晶格传输特性的影响

IF 11.7 1区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES
Le Wang, Zhifei Yang, Krishna Prasad Koirala, Mark E. Bowden, John W. Freeland, Peter V. Sushko, Cheng-Tai Kuo, Scott A. Chambers, Chongmin Wang, Bharat Jalan, Yingge Du
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引用次数: 0

摘要

电荷在氧化物异质界面上的转移或再分配是一种关键现象,通常会导致诸如二维电子气体和界面铁磁性等显著特性。尽管对lanio3 /LaFeO 3的超晶格和异质结构进行了研究,但电荷转移的方向和大小仍然存在争议,一些人认为由于fe3 + (3d 5)的高稳定性,没有电荷转移。在这里,我们合成了一系列外延LaNiO 3 /LaFeO 3超晶格,并通过密度泛函理论模拟和Ni和Fe氧化态变化的光谱证据证明了界面附近Fe到Ni的部分(高达~0.5 e−/界面单位电池)电荷转移。从LaFeO 3到LaNiO 3的电子转移以及随后Fe 3d带的重排在LaFeO 3层内产生了意想不到的金属基态,强烈影响了跨超晶格的平面内输运性质。此外,我们建立了界面电荷转移与平面内电输运性质之间的直接关联,为设计具有新兴性质的功能氧化物异质结构提供了见解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Interfacial charge transfer and its impact on transport properties of LaNiO3/LaFeO3 superlattices

Interfacial charge transfer and its impact on transport properties of LaNiO3/LaFeO3 superlattices
Charge transfer or redistribution at oxide heterointerfaces is a critical phenomenon, often leading to remarkable properties such as two-dimensional electron gas and interfacial ferromagnetism. Despite studies on LaNiO3/LaFeO3 superlattices and heterostructures, the direction and magnitude of the charge transfer remain debated, with some suggesting no charge transfer due to the high stability of Fe3+ (3d5). Here, we synthesized a series of epitaxial LaNiO3/LaFeO3 superlattices and demonstrated partial (up to ~0.5 e/interface unit cell) charge transfer from Fe to Ni near the interface, supported by density functional theory simulations and spectroscopic evidence of changes in Ni and Fe oxidation states. The electron transfer from LaFeO3 to LaNiO3 and the subsequent rearrangement of the Fe 3d band create an unexpected metallic ground state within the LaFeO3 layer, strongly influencing the in-plane transport properties across the superlattice. Moreover, we establish a direct correlation between interfacial charge transfer and in-plane electrical transport properties, providing insights for designing functional oxide heterostructures with emerging properties.
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来源期刊
Science Advances
Science Advances 综合性期刊-综合性期刊
CiteScore
21.40
自引率
1.50%
发文量
1937
审稿时长
29 weeks
期刊介绍: Science Advances, an open-access journal by AAAS, publishes impactful research in diverse scientific areas. It aims for fair, fast, and expert peer review, providing freely accessible research to readers. Led by distinguished scientists, the journal supports AAAS's mission by extending Science magazine's capacity to identify and promote significant advances. Evolving digital publishing technologies play a crucial role in advancing AAAS's global mission for science communication and benefitting humankind.
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