Allan F. C. Rossini, Ana Carolina A. Muraca, Gleison A. Casagrande, Cristiano Raminelli
{"title":"Correction to “Total Syntheses of Aporphine Alkaloids via Benzyne Chemistry: An Approach to the Formation of Aporphine Cores”","authors":"Allan F. C. Rossini, Ana Carolina A. Muraca, Gleison A. Casagrande, Cristiano Raminelli","doi":"10.1021/acs.joc.4c02931","DOIUrl":null,"url":null,"abstract":"For 1,2,11-trimethoxy-6-methyl-5,6,6a,7-tetrahydro-4<i>H</i>-dibenzo[<i>de</i>,<i>g</i>]quinoline (<b>5</b>), the correct <sup>1</sup>H and <sup>13</sup>C NMR data presented below should be considered instead of those presented in the original paper. In addition, for compound <b>5</b>, the correct <sup>1</sup>H NMR spectrum presented in the revised Supporting Information should be considered instead of that presented in the original Supporting Information. <sup>1</sup>H NMR (300 MHz, CDCl<sub>3</sub>) δ 7.19–7.13 (m, 1H), 6.85–6.81 (m, 2H), 6.57 (s, 1H), 3.81 (s, 3H), 3.80 (s, 3H), 3.53 (s, 3H), 3.05–2.94 (m, 3H), 2.87 (d, <i>J</i> = 13.4 Hz, 1H), 2.60 (dd, <i>J</i> = 16.2, 3.6 Hz, 1H), 2.47 (s, 3H), 2.44–2.35 (m, 2H); <sup>13</sup>C NMR (75 MHz, CDCl<sub>3</sub>) δ 156.7, 151.7, 145.5, 138.8, 128.6, 128.2, 127.2, 124.3, 121.2, 119.7, 110.9, 110.0, 62.9, 60.8, 55.8, 55.6, 52.9, 43.7, 35.8, 28.5. The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.joc.4c02931. Copies of NMR spectra and single-crystal X-ray diffraction data (PDF) Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html. This article has not yet been cited by other publications.","PeriodicalId":57,"journal":{"name":"Journal of Organic Chemistry","volume":"55 1","pages":""},"PeriodicalIF":3.3000,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Organic Chemistry","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1021/acs.joc.4c02931","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Correction to “Total Syntheses of Aporphine Alkaloids via Benzyne Chemistry: An Approach to the Formation of Aporphine Cores”
For 1,2,11-trimethoxy-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline (5), the correct 1H and 13C NMR data presented below should be considered instead of those presented in the original paper. In addition, for compound 5, the correct 1H NMR spectrum presented in the revised Supporting Information should be considered instead of that presented in the original Supporting Information. 1H NMR (300 MHz, CDCl3) δ 7.19–7.13 (m, 1H), 6.85–6.81 (m, 2H), 6.57 (s, 1H), 3.81 (s, 3H), 3.80 (s, 3H), 3.53 (s, 3H), 3.05–2.94 (m, 3H), 2.87 (d, J = 13.4 Hz, 1H), 2.60 (dd, J = 16.2, 3.6 Hz, 1H), 2.47 (s, 3H), 2.44–2.35 (m, 2H); 13C NMR (75 MHz, CDCl3) δ 156.7, 151.7, 145.5, 138.8, 128.6, 128.2, 127.2, 124.3, 121.2, 119.7, 110.9, 110.0, 62.9, 60.8, 55.8, 55.6, 52.9, 43.7, 35.8, 28.5. The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.joc.4c02931. Copies of NMR spectra and single-crystal X-ray diffraction data (PDF) Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html. This article has not yet been cited by other publications.
期刊介绍:
Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.