卟啉的合成与结构（2.1.2.1）弓

IF 4.7 2区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Inorganic Chemistry Pub Date : 2024-12-18 DOI:10.1021/acs.inorgchem.4c03813

Jinrong Wu, Daichi Yoshikawa, Daiki Kuzuhara, Zijian Gao, Yemei Wang, Hongling Huang, Fengxian Qiu, Songlin Xue

{"title":"卟啉的合成与结构（2.1.2.1）弓","authors":"Jinrong Wu, Daichi Yoshikawa, Daiki Kuzuhara, Zijian Gao, Yemei Wang, Hongling Huang, Fengxian Qiu, Songlin Xue","doi":"10.1021/acs.inorgchem.4c03813","DOIUrl":null,"url":null,"abstract":"A new series of porphyrin(2.1.2.1) arches have been successfully synthesized by using porphyrin(2.1.2.1) as natural “arch limbs” for the construction of the arches. X-ray single-crystal diffraction revealed that the porphyrin(2.1.2.1) derivatives have a beautiful bow-shaped structure. The strong, rigid structure of the porphyrin(2.1.2.1) bow prevents hydrogenation with the Lindlar catalyst. The heterogeneous electrocatalytic HER activity of the porphyrin(2.1.2.1) bow indicated that the “bowstring” butadiyne-bridge reduced the HER capacity.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"47 21 1","pages":""},"PeriodicalIF":4.7000,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Structure of Porphyrin(2.1.2.1) Bows\",\"authors\":\"Jinrong Wu, Daichi Yoshikawa, Daiki Kuzuhara, Zijian Gao, Yemei Wang, Hongling Huang, Fengxian Qiu, Songlin Xue\",\"doi\":\"10.1021/acs.inorgchem.4c03813\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A new series of porphyrin(2.1.2.1) arches have been successfully synthesized by using porphyrin(2.1.2.1) as natural “arch limbs” for the construction of the arches. X-ray single-crystal diffraction revealed that the porphyrin(2.1.2.1) derivatives have a beautiful bow-shaped structure. The strong, rigid structure of the porphyrin(2.1.2.1) bow prevents hydrogenation with the Lindlar catalyst. The heterogeneous electrocatalytic HER activity of the porphyrin(2.1.2.1) bow indicated that the “bowstring” butadiyne-bridge reduced the HER capacity.\",\"PeriodicalId\":40,\"journal\":{\"name\":\"Inorganic Chemistry\",\"volume\":\"47 21 1\",\"pages\":\"\"},\"PeriodicalIF\":4.7000,\"publicationDate\":\"2024-12-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1021/acs.inorgchem.4c03813\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.inorgchem.4c03813","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

摘要

以卟啉（2.1.2.1）为天然“弓肢”，成功合成了一系列新的卟啉（2.1.2.1）弓。x射线单晶衍射结果表明，卟啉（2.1.2.1）衍生物具有美丽的弓形结构。卟啉（2.1.2.1）的坚固刚性结构阻止了Lindlar催化剂的氢化反应。卟啉（2.1.2.1）弓的多相电催化HER活性表明，“弓弦”丁二烯桥降低了HER容量。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synthesis and Structure of Porphyrin(2.1.2.1) Bows

查看原文本刊更多论文

Synthesis and Structure of Porphyrin(2.1.2.1) Bows

A new series of porphyrin(2.1.2.1) arches have been successfully synthesized by using porphyrin(2.1.2.1) as natural “arch limbs” for the construction of the arches. X-ray single-crystal diffraction revealed that the porphyrin(2.1.2.1) derivatives have a beautiful bow-shaped structure. The strong, rigid structure of the porphyrin(2.1.2.1) bow prevents hydrogenation with the Lindlar catalyst. The heterogeneous electrocatalytic HER activity of the porphyrin(2.1.2.1) bow indicated that the “bowstring” butadiyne-bridge reduced the HER capacity.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Inorganic Chemistry 化学-无机化学与核化学

CiteScore

7.60

自引率

13.00%

发文量

1960

审稿时长

1.9 months

期刊介绍： Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.