{"title":"基于智能手机的荧光传感系统,用于同时目视检测铬(Ⅲ)和铜(Ⅱ)离子。","authors":"Runpeng Dong, Fangkai Du, Yanzhen Sun, Jinli Lin","doi":"10.1016/j.saa.2024.125573","DOIUrl":null,"url":null,"abstract":"<div><div>In this work, we developed a highly accurate and sensitive two-emission fluorescence sensor, integrated with a smartphone, for the rapid detection of Cu<sup>2+</sup> and Cr<sup>3+</sup> in aqueous solution. This sensor comprised AgInS/ZnS quantum dots (AIS/ZnS QDs) and metal-AIEgen frameworks (MAFs). Upon mixing in a specific ratio, the hybrid system can emit a white light when exposed to a UV lamp (365 nm). The system demonstrates distinct fluorescence variations upon interaction with Cr<sup>3+</sup> or Cu<sup>2+</sup>. Specifically, the sensor transitions from white to red or blue when exposed to Cr<sup>3+</sup> or Cu<sup>2+</sup>, respectively. By utilizing smartphone color recognition software to measure the ratio of red to blue (R/B) value of the solution, the detection ranges of the dual response sensor for Cr<sup>3+</sup> and Cu<sup>2+</sup> are established at 250–5000 nM and 100–2500 nM, with detection limits of 168.4 nM and 101.1 nM, respectively. The practicality of the sensor is validated through quantitative measurement of RGB values from real water samples, including drinking water, tap water, and lake water. Consequently, this sensor exhibits significant potential for point-of-care detection, attributable to its low cost, portability, and high specificity and sensitivity.</div></div>","PeriodicalId":433,"journal":{"name":"Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy","volume":"329 ","pages":"Article 125573"},"PeriodicalIF":4.3000,"publicationDate":"2024-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A smartphone-based fluorescent sensing system for simultaneous visual detection of chromium(Ⅲ) and copper(Ⅱ) ions\",\"authors\":\"Runpeng Dong, Fangkai Du, Yanzhen Sun, Jinli Lin\",\"doi\":\"10.1016/j.saa.2024.125573\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In this work, we developed a highly accurate and sensitive two-emission fluorescence sensor, integrated with a smartphone, for the rapid detection of Cu<sup>2+</sup> and Cr<sup>3+</sup> in aqueous solution. This sensor comprised AgInS/ZnS quantum dots (AIS/ZnS QDs) and metal-AIEgen frameworks (MAFs). Upon mixing in a specific ratio, the hybrid system can emit a white light when exposed to a UV lamp (365 nm). The system demonstrates distinct fluorescence variations upon interaction with Cr<sup>3+</sup> or Cu<sup>2+</sup>. Specifically, the sensor transitions from white to red or blue when exposed to Cr<sup>3+</sup> or Cu<sup>2+</sup>, respectively. By utilizing smartphone color recognition software to measure the ratio of red to blue (R/B) value of the solution, the detection ranges of the dual response sensor for Cr<sup>3+</sup> and Cu<sup>2+</sup> are established at 250–5000 nM and 100–2500 nM, with detection limits of 168.4 nM and 101.1 nM, respectively. The practicality of the sensor is validated through quantitative measurement of RGB values from real water samples, including drinking water, tap water, and lake water. Consequently, this sensor exhibits significant potential for point-of-care detection, attributable to its low cost, portability, and high specificity and sensitivity.</div></div>\",\"PeriodicalId\":433,\"journal\":{\"name\":\"Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy\",\"volume\":\"329 \",\"pages\":\"Article 125573\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-12-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1386142524017396\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"SPECTROSCOPY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1386142524017396","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"SPECTROSCOPY","Score":null,"Total":0}
A smartphone-based fluorescent sensing system for simultaneous visual detection of chromium(Ⅲ) and copper(Ⅱ) ions
In this work, we developed a highly accurate and sensitive two-emission fluorescence sensor, integrated with a smartphone, for the rapid detection of Cu2+ and Cr3+ in aqueous solution. This sensor comprised AgInS/ZnS quantum dots (AIS/ZnS QDs) and metal-AIEgen frameworks (MAFs). Upon mixing in a specific ratio, the hybrid system can emit a white light when exposed to a UV lamp (365 nm). The system demonstrates distinct fluorescence variations upon interaction with Cr3+ or Cu2+. Specifically, the sensor transitions from white to red or blue when exposed to Cr3+ or Cu2+, respectively. By utilizing smartphone color recognition software to measure the ratio of red to blue (R/B) value of the solution, the detection ranges of the dual response sensor for Cr3+ and Cu2+ are established at 250–5000 nM and 100–2500 nM, with detection limits of 168.4 nM and 101.1 nM, respectively. The practicality of the sensor is validated through quantitative measurement of RGB values from real water samples, including drinking water, tap water, and lake water. Consequently, this sensor exhibits significant potential for point-of-care detection, attributable to its low cost, portability, and high specificity and sensitivity.
期刊介绍:
Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy (SAA) is an interdisciplinary journal which spans from basic to applied aspects of optical spectroscopy in chemistry, medicine, biology, and materials science.
The journal publishes original scientific papers that feature high-quality spectroscopic data and analysis. From the broad range of optical spectroscopies, the emphasis is on electronic, vibrational or rotational spectra of molecules, rather than on spectroscopy based on magnetic moments.
Criteria for publication in SAA are novelty, uniqueness, and outstanding quality. Routine applications of spectroscopic techniques and computational methods are not appropriate.
Topics of particular interest of Spectrochimica Acta Part A include, but are not limited to:
Spectroscopy and dynamics of bioanalytical, biomedical, environmental, and atmospheric sciences,
Novel experimental techniques or instrumentation for molecular spectroscopy,
Novel theoretical and computational methods,
Novel applications in photochemistry and photobiology,
Novel interpretational approaches as well as advances in data analysis based on electronic or vibrational spectroscopy.