基于智能手机的荧光传感系统,用于同时目视检测铬(Ⅲ)和铜(Ⅱ)离子。

IF 4.3 2区 化学 Q1 SPECTROSCOPY
Runpeng Dong, Fangkai Du, Yanzhen Sun, Jinli Lin
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引用次数: 0

摘要

在这项工作中,我们开发了一种与智能手机集成的高精度、高灵敏度的双发射荧光传感器,用于快速检测水溶液中的 Cu2+ 和 Cr3+。该传感器由 AgInS/ZnS 量子点(AIS/ZnS QDs)和金属-AIEgen 框架(MAFs)组成。按特定比例混合后,混合系统在紫外灯(365 纳米)照射下可发出白光。该系统在与 Cr3+ 或 Cu2+ 相互作用时会产生明显的荧光变化。具体来说,当接触到 Cr3+ 或 Cu2+ 时,传感器会分别从白色过渡到红色或蓝色。通过利用智能手机颜色识别软件测量溶液的红蓝比值(R/B),确定了双响应传感器对 Cr3+ 和 Cu2+ 的检测范围分别为 250-5000 nM 和 100-2500 nM,检测限分别为 168.4 nM 和 101.1 nM。通过对真实水样(包括饮用水、自来水和湖水)的 RGB 值进行定量测量,验证了该传感器的实用性。因此,这种传感器因其低成本、便携性、高特异性和高灵敏度而在护理点检测方面展现出巨大的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

A smartphone-based fluorescent sensing system for simultaneous visual detection of chromium(Ⅲ) and copper(Ⅱ) ions

A smartphone-based fluorescent sensing system for simultaneous visual detection of chromium(Ⅲ) and copper(Ⅱ) ions
In this work, we developed a highly accurate and sensitive two-emission fluorescence sensor, integrated with a smartphone, for the rapid detection of Cu2+ and Cr3+ in aqueous solution. This sensor comprised AgInS/ZnS quantum dots (AIS/ZnS QDs) and metal-AIEgen frameworks (MAFs). Upon mixing in a specific ratio, the hybrid system can emit a white light when exposed to a UV lamp (365 nm). The system demonstrates distinct fluorescence variations upon interaction with Cr3+ or Cu2+. Specifically, the sensor transitions from white to red or blue when exposed to Cr3+ or Cu2+, respectively. By utilizing smartphone color recognition software to measure the ratio of red to blue (R/B) value of the solution, the detection ranges of the dual response sensor for Cr3+ and Cu2+ are established at 250–5000 nM and 100–2500 nM, with detection limits of 168.4 nM and 101.1 nM, respectively. The practicality of the sensor is validated through quantitative measurement of RGB values from real water samples, including drinking water, tap water, and lake water. Consequently, this sensor exhibits significant potential for point-of-care detection, attributable to its low cost, portability, and high specificity and sensitivity.
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来源期刊
CiteScore
8.40
自引率
11.40%
发文量
1364
审稿时长
40 days
期刊介绍: Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy (SAA) is an interdisciplinary journal which spans from basic to applied aspects of optical spectroscopy in chemistry, medicine, biology, and materials science. The journal publishes original scientific papers that feature high-quality spectroscopic data and analysis. From the broad range of optical spectroscopies, the emphasis is on electronic, vibrational or rotational spectra of molecules, rather than on spectroscopy based on magnetic moments. Criteria for publication in SAA are novelty, uniqueness, and outstanding quality. Routine applications of spectroscopic techniques and computational methods are not appropriate. Topics of particular interest of Spectrochimica Acta Part A include, but are not limited to: Spectroscopy and dynamics of bioanalytical, biomedical, environmental, and atmospheric sciences, Novel experimental techniques or instrumentation for molecular spectroscopy, Novel theoretical and computational methods, Novel applications in photochemistry and photobiology, Novel interpretational approaches as well as advances in data analysis based on electronic or vibrational spectroscopy.
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